Water as an oxygen source in the generation of mononuclear nonheme iron(IV) oxo complexes

Yong Min Lee; Sunder N. Dhuri; Sarvesh C. Sawant; Jaeheung Cho; Minoru Kubo; Takashi Ogura; Shunichi Fukuzumi; Wonwoo Nam

doi:10.1002/anie.200805670

Water as an oxygen source in the generation of mononuclear nonheme iron(IV) oxo complexes

Yong Min Lee, Sunder N. Dhuri, Sarvesh C. Sawant, Jaeheung Cho, Minoru Kubo, Takashi Ogura, Shunichi Fukuzumi, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

89 Scopus citations

Abstract

Give me an "O"! Mononuclear nonheme iron(IV) oxo complexes have been generated using water as an oxygen source and cerium(IV) as an oxidant. The high-yield oxygenation of organic substrates in this system (see picture, Fe green, O red, N blue, C gray) is catalyzed by iron(II) complexes. The source of oxygen in the iron(IV) oxo complexes and the oxygenated products has been assigned unambiguously by isotopic labeling experiments.

Original language	English
Pages (from-to)	1803-1806
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	10
DOIs	https://doi.org/10.1002/anie.200805670
State	Published - 23 Feb 2009

Keywords

Bioinorganic chemistry
Enzyme models
Iron
Oxygenation
Reaction mechanisms

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AU - Lee, Yong Min

AU - Dhuri, Sunder N.

AU - Sawant, Sarvesh C.

AU - Cho, Jaeheung

AU - Kubo, Minoru

AU - Ogura, Takashi

AU - Fukuzumi, Shunichi

AU - Nam, Wonwoo

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AB - Give me an "O"! Mononuclear nonheme iron(IV) oxo complexes have been generated using water as an oxygen source and cerium(IV) as an oxidant. The high-yield oxygenation of organic substrates in this system (see picture, Fe green, O red, N blue, C gray) is catalyzed by iron(II) complexes. The source of oxygen in the iron(IV) oxo complexes and the oxygenated products has been assigned unambiguously by isotopic labeling experiments.

KW - Bioinorganic chemistry

KW - Enzyme models

KW - Iron

KW - Oxygenation

KW - Reaction mechanisms

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Water as an oxygen source in the generation of mononuclear nonheme iron(IV) oxo complexes

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Keywords

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