Volume contractions induced by crosslinking: A novel route to nanoporous polymer films

Unyong Jeong; Du Yeol Ryu; Jin Kon Kim; Dong Ha Kim; Thomas P. Russell; Craig J. Hawker

doi:10.1002/adma.200304401

Volume contractions induced by crosslinking: A novel route to nanoporous polymer films

Unyong Jeong, Du Yeol Ryu, Jin Kon Kim, Dong Ha Kim, Thomas P. Russell, Craig J. Hawker

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

90 Scopus citations

Abstract

Producing nanopores in block copolymer films by crosslinking the matrix was shown to be very simple, highly reproducible, and predictable. Via this route, the original ordering of the copolymer was maintained, providing a template in which nanoscopic holes can be produced. Thus, the results present a unique method by which the size limit of the pores in block copolymer thin films can be extended well beyond that achievable using neat block copolymer itself.

Original language	English
Pages (from-to)	1247-1250
Number of pages	4
Journal	Advanced Materials
Volume	15
Issue number	15
DOIs	https://doi.org/10.1002/adma.200304401
State	Published - 5 Aug 2003

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title = "Volume contractions induced by crosslinking: A novel route to nanoporous polymer films",

abstract = "Producing nanopores in block copolymer films by crosslinking the matrix was shown to be very simple, highly reproducible, and predictable. Via this route, the original ordering of the copolymer was maintained, providing a template in which nanoscopic holes can be produced. Thus, the results present a unique method by which the size limit of the pores in block copolymer thin films can be extended well beyond that achievable using neat block copolymer itself.",

author = "Unyong Jeong and Ryu, {Du Yeol} and Kim, {Jin Kon} and Kim, {Dong Ha} and Russell, {Thomas P.} and Hawker, {Craig J.}",

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AU - Ryu, Du Yeol

AU - Kim, Jin Kon

AU - Kim, Dong Ha

AU - Russell, Thomas P.

AU - Hawker, Craig J.

PY - 2003/8/5

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AB - Producing nanopores in block copolymer films by crosslinking the matrix was shown to be very simple, highly reproducible, and predictable. Via this route, the original ordering of the copolymer was maintained, providing a template in which nanoscopic holes can be produced. Thus, the results present a unique method by which the size limit of the pores in block copolymer thin films can be extended well beyond that achievable using neat block copolymer itself.

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Volume contractions induced by crosslinking: A novel route to nanoporous polymer films

Abstract

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