Visible-light-induced oxygenation of benzene by the triplet excited state of 2,3-dichloro-5,6-dicyano-p-benzoquinone

Kei Ohkubo; Atsushi Fujimoto; Shunichi Fukuzumi

doi:10.1021/ja402303k

Visible-light-induced oxygenation of benzene by the triplet excited state of 2,3-dichloro-5,6-dicyano-p-benzoquinone

Kei Ohkubo
, Atsushi Fujimoto
, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

251 Scopus citations

Abstract

Photocatalytic oxygenation of benzene to phenol occurs under visible-light irradiation of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in an oxygen-saturated acetonitrile solution of benzene and tert-butyl nitrite. The photocatalytic reaction is initiated by photoinduced electron transfer from benzene to the triplet excited state of DDQ.

Original language	English
Pages (from-to)	5368-5371
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	14
DOIs	https://doi.org/10.1021/ja402303k
State	Published - 10 Apr 2013

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title = "Visible-light-induced oxygenation of benzene by the triplet excited state of 2,3-dichloro-5,6-dicyano-p-benzoquinone",

abstract = "Photocatalytic oxygenation of benzene to phenol occurs under visible-light irradiation of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in an oxygen-saturated acetonitrile solution of benzene and tert-butyl nitrite. The photocatalytic reaction is initiated by photoinduced electron transfer from benzene to the triplet excited state of DDQ.",

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journal = "Journal of the American Chemical Society",

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T1 - Visible-light-induced oxygenation of benzene by the triplet excited state of 2,3-dichloro-5,6-dicyano-p-benzoquinone

AU - Ohkubo, Kei

AU - Fujimoto, Atsushi

AU - Fukuzumi, Shunichi

PY - 2013/4/10

Y1 - 2013/4/10

N2 - Photocatalytic oxygenation of benzene to phenol occurs under visible-light irradiation of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in an oxygen-saturated acetonitrile solution of benzene and tert-butyl nitrite. The photocatalytic reaction is initiated by photoinduced electron transfer from benzene to the triplet excited state of DDQ.

AB - Photocatalytic oxygenation of benzene to phenol occurs under visible-light irradiation of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in an oxygen-saturated acetonitrile solution of benzene and tert-butyl nitrite. The photocatalytic reaction is initiated by photoinduced electron transfer from benzene to the triplet excited state of DDQ.

UR - https://www.scopus.com/pages/publications/84876013113

U2 - 10.1021/ja402303k

DO - 10.1021/ja402303k

M3 - Article

C2 - 23534829

AN - SCOPUS:84876013113

SN - 0002-7863

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SP - 5368

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 14

ER -

Visible-light-induced oxygenation of benzene by the triplet excited state of 2,3-dichloro-5,6-dicyano-p-benzoquinone

Abstract

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