Unique determination of the hyperpolarizability tensor ratio through a depolarized hyper-Rayleigh scattering under an external electric field

Jisoo Hwang; Byoungchoo Park; H. J. Chang; J. W. Wu

doi:10.1117/12.499226

Unique determination of the hyperpolarizability tensor ratio through a depolarized hyper-Rayleigh scattering under an external electric field

Jisoo Hwang, Byoungchoo Park, H. J. Chang, J. W. Wu

Department of Physics

Research output: Contribution to journal › Conference article › peer-review

Abstract

We analyzed the depolarized hyper-Rayleigh scattering from molecular system with a partial macroscopic polar ordering. It is shown that hyperpolarizability tensor ratio and molecular dipole moment can be determined simultaneously by the depolarization measurement as a function of the external field strength. As an experimental example, we performed a quantitative analysis of the electric-field dependent depolarized hyper-Rayleigh signal from a poly-γ-benzyl-L-glutamate solution, obtaining the dipole moment and the ratio of hyperpolarizability components as 4.0 Debye and β ₃₁₁/β₃₃₃ = -0.81.

Original language	English
Pages (from-to)	490-494
Number of pages	5
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	4991
DOIs	https://doi.org/10.1117/12.499226
State	Published - 2003
Event	PROCEEDINGS OF SPIE SPIE - The International Society for Optical Engineering: Organic Photonic Materials and Devices V - San Jose, CA, United States Duration: 27 Jan 2003 → 30 Jan 2003

Keywords

HyperRayleigh Scattering
Nonlinear Optics

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10.1117/12.499226

Cite this

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title = "Unique determination of the hyperpolarizability tensor ratio through a depolarized hyper-Rayleigh scattering under an external electric field",

abstract = "We analyzed the depolarized hyper-Rayleigh scattering from molecular system with a partial macroscopic polar ordering. It is shown that hyperpolarizability tensor ratio and molecular dipole moment can be determined simultaneously by the depolarization measurement as a function of the external field strength. As an experimental example, we performed a quantitative analysis of the electric-field dependent depolarized hyper-Rayleigh signal from a poly-γ-benzyl-L-glutamate solution, obtaining the dipole moment and the ratio of hyperpolarizability components as 4.0 Debye and β 311/β333 = -0.81.",

keywords = "HyperRayleigh Scattering, Nonlinear Optics",

author = "Jisoo Hwang and Byoungchoo Park and Chang, {H. J.} and Wu, {J. W.}",

year = "2003",

doi = "10.1117/12.499226",

language = "English",

volume = "4991",

pages = "490--494",

journal = "Proceedings of SPIE - The International Society for Optical Engineering",

issn = "0277-786X",

publisher = "SPIE",

note = "PROCEEDINGS OF SPIE SPIE - The International Society for Optical Engineering: Organic Photonic Materials and Devices V ; Conference date: 27-01-2003 Through 30-01-2003",

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Unique determination of the hyperpolarizability tensor ratio through a depolarized hyper-Rayleigh scattering under an external electric field. / Hwang, Jisoo; Park, Byoungchoo; Chang, H. J. et al.
In: Proceedings of SPIE - The International Society for Optical Engineering, Vol. 4991, 2003, p. 490-494.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Unique determination of the hyperpolarizability tensor ratio through a depolarized hyper-Rayleigh scattering under an external electric field

AU - Hwang, Jisoo

AU - Park, Byoungchoo

AU - Chang, H. J.

AU - Wu, J. W.

PY - 2003

Y1 - 2003

N2 - We analyzed the depolarized hyper-Rayleigh scattering from molecular system with a partial macroscopic polar ordering. It is shown that hyperpolarizability tensor ratio and molecular dipole moment can be determined simultaneously by the depolarization measurement as a function of the external field strength. As an experimental example, we performed a quantitative analysis of the electric-field dependent depolarized hyper-Rayleigh signal from a poly-γ-benzyl-L-glutamate solution, obtaining the dipole moment and the ratio of hyperpolarizability components as 4.0 Debye and β 311/β333 = -0.81.

AB - We analyzed the depolarized hyper-Rayleigh scattering from molecular system with a partial macroscopic polar ordering. It is shown that hyperpolarizability tensor ratio and molecular dipole moment can be determined simultaneously by the depolarization measurement as a function of the external field strength. As an experimental example, we performed a quantitative analysis of the electric-field dependent depolarized hyper-Rayleigh signal from a poly-γ-benzyl-L-glutamate solution, obtaining the dipole moment and the ratio of hyperpolarizability components as 4.0 Debye and β 311/β333 = -0.81.

KW - HyperRayleigh Scattering

KW - Nonlinear Optics

UR - http://www.scopus.com/inward/record.url?scp=0242524526&partnerID=8YFLogxK

U2 - 10.1117/12.499226

DO - 10.1117/12.499226

M3 - Conference article

AN - SCOPUS:0242524526

SN - 0277-786X

VL - 4991

SP - 490

EP - 494

JO - Proceedings of SPIE - The International Society for Optical Engineering

JF - Proceedings of SPIE - The International Society for Optical Engineering

T2 - PROCEEDINGS OF SPIE SPIE - The International Society for Optical Engineering: Organic Photonic Materials and Devices V

Y2 - 27 January 2003 through 30 January 2003

ER -

Unique determination of the hyperpolarizability tensor ratio through a depolarized hyper-Rayleigh scattering under an external electric field

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