Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst

Kei Ohkubo; Kensaku Hirose; Shunichi Fukuzumi

doi:10.1039/c6ra05993g

Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst

Kei Ohkubo, Kensaku Hirose, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The two-phase photocatalytic oxidation of toluene and p-xylene by dioxygen occurred efficiently using 3-cyano-1-decylquinolinium hexafluorophosphate (DeQuCN⁺PF₆^-) as an organic photocatalyst. When toluene and p-xylene were used as the solvent with 2% H₂O, the oxygenated products were produced in the organic phase and hydrogen peroxide was produced in the aqueous phase at high turnover numbers.

Original language	English
Pages (from-to)	41011-41014
Number of pages	4
Journal	RSC Advances
Volume	6
Issue number	47
DOIs	https://doi.org/10.1039/c6ra05993g
State	Published - 2016

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2016.

Access to Document

10.1039/c6ra05993g

Cite this

@article{95596c76d6e14e1ebffbbc9b4a9d1f9d,

title = "Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst",

abstract = "The two-phase photocatalytic oxidation of toluene and p-xylene by dioxygen occurred efficiently using 3-cyano-1-decylquinolinium hexafluorophosphate (DeQuCN+PF6-) as an organic photocatalyst. When toluene and p-xylene were used as the solvent with 2\% H2O, the oxygenated products were produced in the organic phase and hydrogen peroxide was produced in the aqueous phase at high turnover numbers.",

author = "Kei Ohkubo and Kensaku Hirose and Shunichi Fukuzumi",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c6ra05993g",

language = "English",

volume = "6",

pages = "41011--41014",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "47",

}

TY - JOUR

T1 - Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst

AU - Ohkubo, Kei

AU - Hirose, Kensaku

AU - Fukuzumi, Shunichi

N1 - Publisher Copyright: © The Royal Society of Chemistry 2016.

PY - 2016

Y1 - 2016

N2 - The two-phase photocatalytic oxidation of toluene and p-xylene by dioxygen occurred efficiently using 3-cyano-1-decylquinolinium hexafluorophosphate (DeQuCN+PF6-) as an organic photocatalyst. When toluene and p-xylene were used as the solvent with 2% H2O, the oxygenated products were produced in the organic phase and hydrogen peroxide was produced in the aqueous phase at high turnover numbers.

AB - The two-phase photocatalytic oxidation of toluene and p-xylene by dioxygen occurred efficiently using 3-cyano-1-decylquinolinium hexafluorophosphate (DeQuCN+PF6-) as an organic photocatalyst. When toluene and p-xylene were used as the solvent with 2% H2O, the oxygenated products were produced in the organic phase and hydrogen peroxide was produced in the aqueous phase at high turnover numbers.

UR - https://www.scopus.com/pages/publications/84966326661

U2 - 10.1039/c6ra05993g

DO - 10.1039/c6ra05993g

M3 - Article

AN - SCOPUS:84966326661

SN - 2046-2069

VL - 6

SP - 41011

EP - 41014

JO - RSC Advances

JF - RSC Advances

IS - 47

ER -

Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst

Abstract

Bibliographical note

Access to Document

Fingerprint

Cite this