Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst

Kei Ohkubo; Kensaku Hirose; Shunichi Fukuzumi

doi:10.1039/c6ra05993g

Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst

Kei Ohkubo, Kensaku Hirose, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The two-phase photocatalytic oxidation of toluene and p-xylene by dioxygen occurred efficiently using 3-cyano-1-decylquinolinium hexafluorophosphate (DeQuCN⁺PF₆^-) as an organic photocatalyst. When toluene and p-xylene were used as the solvent with 2% H₂O, the oxygenated products were produced in the organic phase and hydrogen peroxide was produced in the aqueous phase at high turnover numbers.

Original language	English
Pages (from-to)	41011-41014
Number of pages	4
Journal	RSC Advances
Volume	6
Issue number	47
DOIs	https://doi.org/10.1039/c6ra05993g
State	Published - 2016

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© The Royal Society of Chemistry 2016.

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title = "Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst",

abstract = "The two-phase photocatalytic oxidation of toluene and p-xylene by dioxygen occurred efficiently using 3-cyano-1-decylquinolinium hexafluorophosphate (DeQuCN+PF6-) as an organic photocatalyst. When toluene and p-xylene were used as the solvent with 2% H2O, the oxygenated products were produced in the organic phase and hydrogen peroxide was produced in the aqueous phase at high turnover numbers.",

author = "Kei Ohkubo and Kensaku Hirose and Shunichi Fukuzumi",

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AU - Ohkubo, Kei

AU - Hirose, Kensaku

AU - Fukuzumi, Shunichi

N1 - Publisher Copyright: © The Royal Society of Chemistry 2016.

PY - 2016

Y1 - 2016

N2 - The two-phase photocatalytic oxidation of toluene and p-xylene by dioxygen occurred efficiently using 3-cyano-1-decylquinolinium hexafluorophosphate (DeQuCN+PF6-) as an organic photocatalyst. When toluene and p-xylene were used as the solvent with 2% H2O, the oxygenated products were produced in the organic phase and hydrogen peroxide was produced in the aqueous phase at high turnover numbers.

AB - The two-phase photocatalytic oxidation of toluene and p-xylene by dioxygen occurred efficiently using 3-cyano-1-decylquinolinium hexafluorophosphate (DeQuCN+PF6-) as an organic photocatalyst. When toluene and p-xylene were used as the solvent with 2% H2O, the oxygenated products were produced in the organic phase and hydrogen peroxide was produced in the aqueous phase at high turnover numbers.

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U2 - 10.1039/c6ra05993g

DO - 10.1039/c6ra05993g

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ER -

Two-phase oxidation of toluene derivatives by dioxygen using the 3-cyano-1-decylquinolinium ion as a photocatalyst

Abstract

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