Two isomers containing a [Cu(Me2bpzb)] unit: Molecule (0-D) and 1-D

Young Joo Song; Ju Hoon Lee; Hyo Geun Koo; Tae Geum Lee; Sung Hyun Myoung; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1016/j.inoche.2010.03.039

Two isomers containing a [Cu(Me₂bpzb)] unit: Molecule (0-D) and 1-D

Young Joo Song, Ju Hoon Lee, Hyo Geun Koo, Tae Geum Lee, Sung Hyun Myoung, Cheal Kim, Sung Jin Kim, Youngmee Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Two isomers (molecule 1 and 1-D 2) containing [Cu(Me₂bpzb)] units have been obtained under the different reaction conditions, and their structures have been determined by X-ray crystallography. From the temperature-dependent magnetic data for 2, there was no interaction between Cu²⁺ ions through the ligand. The photoluminescence of the free H₂Me₂bpzb molecule displayed an intense emission band centered at about 482 nm, while complexes 1 and 2 exhibited no obvious emission bands.

Original language	English
Pages (from-to)	753-756
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2010.03.039
State	Published - Jun 2010

Bibliographical note

Funding Information:
Financial support from Korea Ministry Environment “ET-Human resource development Project” and the Korean Science & Engineering Foundation ( R01-2008-000-20704-0 and 2009-0074066 ), the Converging Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2009-0082832 ), and the SRC program of MOST/KOSEF through the Center for Intelligent Nano-Bio Materials at Ewha Womans University ( R11-2005-008-00000-0 ) is gratefully acknowledged.

Keywords

Copper complexes
Isomers
Magnetic susceptibility
One-dimensional chain
Photoluminescence

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10.1016/j.inoche.2010.03.039

Cite this

@article{085883c37df748238c0181c3746dc8d3,

title = "Two isomers containing a [Cu(Me2bpzb)] unit: Molecule (0-D) and 1-D",

abstract = "Two isomers (molecule 1 and 1-D 2) containing [Cu(Me2bpzb)] units have been obtained under the different reaction conditions, and their structures have been determined by X-ray crystallography. From the temperature-dependent magnetic data for 2, there was no interaction between Cu2+ ions through the ligand. The photoluminescence of the free H2Me2bpzb molecule displayed an intense emission band centered at about 482 nm, while complexes 1 and 2 exhibited no obvious emission bands.",

keywords = "Copper complexes, Isomers, Magnetic susceptibility, One-dimensional chain, Photoluminescence",

author = "Song, {Young Joo} and Lee, {Ju Hoon} and Koo, {Hyo Geun} and Lee, {Tae Geum} and Myoung, {Sung Hyun} and Cheal Kim and Kim, {Sung Jin} and Youngmee Kim",

note = "Funding Information: Financial support from Korea Ministry Environment “ET-Human resource development Project” and the Korean Science & Engineering Foundation ( R01-2008-000-20704-0 and 2009-0074066 ), the Converging Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2009-0082832 ), and the SRC program of MOST/KOSEF through the Center for Intelligent Nano-Bio Materials at Ewha Womans University ( R11-2005-008-00000-0 ) is gratefully acknowledged. ",

year = "2010",

month = jun,

doi = "10.1016/j.inoche.2010.03.039",

language = "English",

volume = "13",

pages = "753--756",

journal = "Inorganic Chemistry Communications",

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T1 - Two isomers containing a [Cu(Me2bpzb)] unit

T2 - Molecule (0-D) and 1-D

AU - Song, Young Joo

AU - Lee, Ju Hoon

AU - Koo, Hyo Geun

AU - Lee, Tae Geum

AU - Myoung, Sung Hyun

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

N1 - Funding Information: Financial support from Korea Ministry Environment “ET-Human resource development Project” and the Korean Science & Engineering Foundation ( R01-2008-000-20704-0 and 2009-0074066 ), the Converging Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2009-0082832 ), and the SRC program of MOST/KOSEF through the Center for Intelligent Nano-Bio Materials at Ewha Womans University ( R11-2005-008-00000-0 ) is gratefully acknowledged.

PY - 2010/6

Y1 - 2010/6

N2 - Two isomers (molecule 1 and 1-D 2) containing [Cu(Me2bpzb)] units have been obtained under the different reaction conditions, and their structures have been determined by X-ray crystallography. From the temperature-dependent magnetic data for 2, there was no interaction between Cu2+ ions through the ligand. The photoluminescence of the free H2Me2bpzb molecule displayed an intense emission band centered at about 482 nm, while complexes 1 and 2 exhibited no obvious emission bands.

AB - Two isomers (molecule 1 and 1-D 2) containing [Cu(Me2bpzb)] units have been obtained under the different reaction conditions, and their structures have been determined by X-ray crystallography. From the temperature-dependent magnetic data for 2, there was no interaction between Cu2+ ions through the ligand. The photoluminescence of the free H2Me2bpzb molecule displayed an intense emission band centered at about 482 nm, while complexes 1 and 2 exhibited no obvious emission bands.

KW - Copper complexes

KW - Isomers

KW - Magnetic susceptibility

KW - One-dimensional chain

KW - Photoluminescence

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DO - 10.1016/j.inoche.2010.03.039

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