Two-dimensional Fourier-transform electron spin resonance in complex fluids

Sanghyuk Lee; Baldev R. Patyal; Sunil Saxena; Richard H. Crepeau; Jack H. Freed

doi:10.1016/0009-2614(94)00281-9

Two-dimensional Fourier-transform electron spin resonance in complex fluids

Sanghyuk Lee
, Baldev R. Patyal
, Sunil Saxena
, Richard H. Crepeau
, Jack H. Freed

Department of Life Science

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Two-dimensional Fourier-transform ESR spectra from a complex fluid characterized by very short free induction decay times are reported. They provide enhanced resolution to dynamic molecular structure compared to conventional cw-ESR spectra which are inhomogeneously broadened by the macroscopic disorder. A general theoretical analysis based on the stochastic Liouville equation permits us to accurately determine the microscopic ordering and motional dynamic rates by non-linear least-squares fitting to experiment.

Original language	English
Pages (from-to)	397-406
Number of pages	10
Journal	Chemical Physics Letters
Volume	221
Issue number	5-6
DOIs	https://doi.org/10.1016/0009-2614(94)00281-9
State	Published - 29 Apr 1994

Bibliographical note

Funding Information:
This work was supported by NSF Grants CHE9313167a nd DMR9210638a nd NIH Grants GM25862 and RR07126.C omputationsw ere performed at the Cornell National Supercomputer Facility.

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10.1016/0009-2614(94)00281-9

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@article{093bbffa4c8d4d3ebf9251cbbd30d892,

title = "Two-dimensional Fourier-transform electron spin resonance in complex fluids",

abstract = "Two-dimensional Fourier-transform ESR spectra from a complex fluid characterized by very short free induction decay times are reported. They provide enhanced resolution to dynamic molecular structure compared to conventional cw-ESR spectra which are inhomogeneously broadened by the macroscopic disorder. A general theoretical analysis based on the stochastic Liouville equation permits us to accurately determine the microscopic ordering and motional dynamic rates by non-linear least-squares fitting to experiment.",

author = "Sanghyuk Lee and Patyal, \{Baldev R.\} and Sunil Saxena and Crepeau, \{Richard H.\} and Freed, \{Jack H.\}",

note = "Funding Information: This work was supported by NSF Grants CHE9313167a nd DMR9210638a nd NIH Grants GM25862 and RR07126.C omputationsw ere performed at the Cornell National Supercomputer Facility.",

year = "1994",

month = apr,

day = "29",

doi = "10.1016/0009-2614(94)00281-9",

language = "English",

volume = "221",

pages = "397--406",

journal = "Chemical Physics Letters",

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T1 - Two-dimensional Fourier-transform electron spin resonance in complex fluids

AU - Lee, Sanghyuk

AU - Patyal, Baldev R.

AU - Saxena, Sunil

AU - Crepeau, Richard H.

AU - Freed, Jack H.

N1 - Funding Information: This work was supported by NSF Grants CHE9313167a nd DMR9210638a nd NIH Grants GM25862 and RR07126.C omputationsw ere performed at the Cornell National Supercomputer Facility.

PY - 1994/4/29

Y1 - 1994/4/29

N2 - Two-dimensional Fourier-transform ESR spectra from a complex fluid characterized by very short free induction decay times are reported. They provide enhanced resolution to dynamic molecular structure compared to conventional cw-ESR spectra which are inhomogeneously broadened by the macroscopic disorder. A general theoretical analysis based on the stochastic Liouville equation permits us to accurately determine the microscopic ordering and motional dynamic rates by non-linear least-squares fitting to experiment.

AB - Two-dimensional Fourier-transform ESR spectra from a complex fluid characterized by very short free induction decay times are reported. They provide enhanced resolution to dynamic molecular structure compared to conventional cw-ESR spectra which are inhomogeneously broadened by the macroscopic disorder. A general theoretical analysis based on the stochastic Liouville equation permits us to accurately determine the microscopic ordering and motional dynamic rates by non-linear least-squares fitting to experiment.

UR - https://www.scopus.com/pages/publications/0042588935

U2 - 10.1016/0009-2614(94)00281-9

DO - 10.1016/0009-2614(94)00281-9

M3 - Article

AN - SCOPUS:0042588935

SN - 0009-2614

VL - 221

SP - 397

EP - 406

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5-6

ER -

Two-dimensional Fourier-transform electron spin resonance in complex fluids

Abstract

Bibliographical note

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