Twist-Stabilized, Coiled Carbon Nanotube Yarns with Enhanced Capacitance

Wonkyeong Son, Sungwoo Chun, Jae Myeong Lee, Gichan Jeon, Hyeon Jun Sim, Hyeon Woo Kim, Sung Beom Cho, Dongyun Lee, Junyoung Park, Joonhyeon Jeon, Dongseok Suh, Changsoon Choi

Research output: Contribution to journalArticlepeer-review

29 Scopus citations

Abstract

Coil-structured carbon nanotube (CNT) yarns have recently attracted considerable attention. However, structural instability due to heavy twist insertion, and inherent hydrophobicity restrict its wider application. We report a twist-stable and hydrophilic coiled CNT yarn produced by the facile electrochemical oxidation (ECO) method. The ECO-treated coiled CNT yarn is prepared by applying low potentiostatic voltages (3.0-4.5 V vs Ag/AgCl) between the coiled CNT yarn and a counter electrode immersed in an electrolyte for 10-30 s. Notably, a large volume expansion of the coiled CNT yarns prepared by electrochemical charge injection produces morphological changes, such as surface microbuckling and large reductions in the yarn bias angle and diameter, resulting in the twist-stability of the dried ECO-treated coiled CNT yarns with increased yarn density. The resulting yarns are well functionalized with oxygen-containing groups; they exhibit extrinsic hydrophilicity and significantly improved capacitance (approximately 17-fold). We quantitatively explain the origin of the capacitance improvement using theoretical simulations and experimental observations. Stretchable supercapacitors fabricated with the ECO-treated coiled CNT yarns show high capacitance (12.48 mF/cm and 172.93 mF/cm2, respectively) and great stretchability (80%). Moreover, the ECO-treated coiled CNT yarns are strong enough to be woven into a mask as wearable supercapacitors.

Original languageEnglish
Pages (from-to)2661-2671
Number of pages11
JournalACS Nano
Volume16
Issue number2
DOIs
StatePublished - 22 Feb 2022

Bibliographical note

Funding Information:
This work was supported by Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20194030202320) and the Basic Science Research Programs through the National Research Foundation of Korea (NRF-2021R1A2C2005281).

Publisher Copyright:
© 2022 American Chemical Society

Keywords

  • coiled carbon nanotube yarn
  • electrochemical oxidation
  • hydrophilicity
  • supercapacitor
  • twist-stability

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