Tuning of the flexibility in metal-organic frameworks based on pendant arm macrocycles

Sungeun Jeoung, Songho Lee, Jae Hwa Lee, Soochan Lee, Wonyoung Choe, Dohyun Moon, Hoi Ri Moon

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

An isostructural series of flexible metal-organic frameworks based on macrocycles having diverse pendant arms was developed to tune flexibility depending on functional groups. The pendant arms directing into the pores were found to play a key role in imparting different gate-opening behaviours in the threshold pressure and sorption capacity upon interaction with guest molecules.

Original languageEnglish
Pages (from-to)8832-8835
Number of pages4
JournalChemical Communications
Volume55
Issue number60
DOIs
StatePublished - 2019

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science and ICT (No. NRF-2016R1A5A1009405, NRF-2017R1A2B4008757). X-ray crystallography analysis performed at 2D-SMC beamline (2018-3rd-2D-036) in PLS-II were supported by MSIT and POSTECH.

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

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