Tuning of the flexibility in metal-organic frameworks based on pendant arm macrocycles

Sungeun Jeoung; Songho Lee; Jae Hwa Lee; Soochan Lee; Wonyoung Choe; Dohyun Moon; Hoi Ri Moon

doi:10.1039/c9cc02819f

Tuning of the flexibility in metal-organic frameworks based on pendant arm macrocycles

Sungeun Jeoung, Songho Lee, Jae Hwa Lee, Soochan Lee, Wonyoung Choe, Dohyun Moon, Hoi Ri Moon

Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

An isostructural series of flexible metal-organic frameworks based on macrocycles having diverse pendant arms was developed to tune flexibility depending on functional groups. The pendant arms directing into the pores were found to play a key role in imparting different gate-opening behaviours in the threshold pressure and sorption capacity upon interaction with guest molecules.

Original language	English
Pages (from-to)	8832-8835
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	60
DOIs	https://doi.org/10.1039/c9cc02819f
State	Published - 2019

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science and ICT (No. NRF-2016R1A5A1009405, NRF-2017R1A2B4008757). X-ray crystallography analysis performed at 2D-SMC beamline (2018-3rd-2D-036) in PLS-II were supported by MSIT and POSTECH.

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

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title = "Tuning of the flexibility in metal-organic frameworks based on pendant arm macrocycles",

abstract = "An isostructural series of flexible metal-organic frameworks based on macrocycles having diverse pendant arms was developed to tune flexibility depending on functional groups. The pendant arms directing into the pores were found to play a key role in imparting different gate-opening behaviours in the threshold pressure and sorption capacity upon interaction with guest molecules.",

author = "Sungeun Jeoung and Songho Lee and Lee, {Jae Hwa} and Soochan Lee and Wonyoung Choe and Dohyun Moon and Moon, {Hoi Ri}",

note = "Funding Information: This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science and ICT (No. NRF-2016R1A5A1009405, NRF-2017R1A2B4008757). X-ray crystallography analysis performed at 2D-SMC beamline (2018-3rd-2D-036) in PLS-II were supported by MSIT and POSTECH. Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

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doi = "10.1039/c9cc02819f",

language = "English",

volume = "55",

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AU - Jeoung, Sungeun

AU - Lee, Songho

AU - Lee, Jae Hwa

AU - Lee, Soochan

AU - Choe, Wonyoung

AU - Moon, Dohyun

AU - Moon, Hoi Ri

N1 - Funding Information: This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science and ICT (No. NRF-2016R1A5A1009405, NRF-2017R1A2B4008757). X-ray crystallography analysis performed at 2D-SMC beamline (2018-3rd-2D-036) in PLS-II were supported by MSIT and POSTECH. Publisher Copyright: © 2019 The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - An isostructural series of flexible metal-organic frameworks based on macrocycles having diverse pendant arms was developed to tune flexibility depending on functional groups. The pendant arms directing into the pores were found to play a key role in imparting different gate-opening behaviours in the threshold pressure and sorption capacity upon interaction with guest molecules.

AB - An isostructural series of flexible metal-organic frameworks based on macrocycles having diverse pendant arms was developed to tune flexibility depending on functional groups. The pendant arms directing into the pores were found to play a key role in imparting different gate-opening behaviours in the threshold pressure and sorption capacity upon interaction with guest molecules.

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VL - 55

SP - 8832

EP - 8835

JO - Chemical Communications

JF - Chemical Communications

IS - 60

ER -

Tuning of the flexibility in metal-organic frameworks based on pendant arm macrocycles

Abstract

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