Topology Conversions of Non-Interpenetrated Metal-Organic Frameworks to Doubly Interpenetrated Metal-Organic Frameworks

Seok Jeong; Dongwook Kim; Jeongin Park; Sunyoung Shin; Hyehyun Kim; Gyoung Hwa Jeong; Dohyun Moon; Hoi Ri Moon; Myoung Soo Lah

doi:10.1021/acs.chemmater.6b05277

Topology Conversions of Non-Interpenetrated Metal-Organic Frameworks to Doubly Interpenetrated Metal-Organic Frameworks

Seok Jeong, Dongwook Kim, Jeongin Park, Sunyoung Shin, Hyehyun Kim, Gyoung Hwa Jeong, Dohyun Moon, Hoi Ri Moon, Myoung Soo Lah

Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Non-interpenetrated three-dimensional (3D) metal-organic frameworks (MOFs) with both an interpenetration-favorable (3,5)-c hms topology and an interpenetration-unfavorable (3,5)-c gra topology are converted to doubly interpenetrated analogues with hms-c topology by thermal treatment, even in the absence of solvent. Depending on the conversion temperature and the properties of the pillaring ligand in the non-interpenetrated 3D MOF, which is based on two-dimensional sheets with 3-c hcb topology pillared by neutral ditopic linkers, the pillaring ligands in the interpenetrated MOFs produced are partially removed during the thermal conversions, leading to interpenetrated MOFs that simultaneously contain both micro- and mesopores.

Original language	English
Pages (from-to)	3899-3907
Number of pages	9
Journal	Chemistry of Materials
Volume	29
Issue number	9
DOIs	https://doi.org/10.1021/acs.chemmater.6b05277
State	Published - 9 May 2017

Bibliographical note

Funding Information:
This work was supported by the NRF (2015R1A2A1A15053104, 2015R1D1A1A01056579 and 2016R1A5A1009405) through the National Research Foundation of Korea. The authors acknowledge PAL for beamline use (2015-first-2D-015 and 2015-second-2D-013).

Publisher Copyright:
© 2017 American Chemical Society.

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10.1021/acs.chemmater.6b05277

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title = "Topology Conversions of Non-Interpenetrated Metal-Organic Frameworks to Doubly Interpenetrated Metal-Organic Frameworks",

abstract = "Non-interpenetrated three-dimensional (3D) metal-organic frameworks (MOFs) with both an interpenetration-favorable (3,5)-c hms topology and an interpenetration-unfavorable (3,5)-c gra topology are converted to doubly interpenetrated analogues with hms-c topology by thermal treatment, even in the absence of solvent. Depending on the conversion temperature and the properties of the pillaring ligand in the non-interpenetrated 3D MOF, which is based on two-dimensional sheets with 3-c hcb topology pillared by neutral ditopic linkers, the pillaring ligands in the interpenetrated MOFs produced are partially removed during the thermal conversions, leading to interpenetrated MOFs that simultaneously contain both micro- and mesopores.",

author = "Seok Jeong and Dongwook Kim and Jeongin Park and Sunyoung Shin and Hyehyun Kim and Jeong, {Gyoung Hwa} and Dohyun Moon and Moon, {Hoi Ri} and Lah, {Myoung Soo}",

note = "Funding Information: This work was supported by the NRF (2015R1A2A1A15053104, 2015R1D1A1A01056579 and 2016R1A5A1009405) through the National Research Foundation of Korea. The authors acknowledge PAL for beamline use (2015-first-2D-015 and 2015-second-2D-013). Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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doi = "10.1021/acs.chemmater.6b05277",

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AU - Jeong, Seok

AU - Kim, Dongwook

AU - Park, Jeongin

AU - Shin, Sunyoung

AU - Kim, Hyehyun

AU - Jeong, Gyoung Hwa

AU - Moon, Dohyun

AU - Moon, Hoi Ri

AU - Lah, Myoung Soo

N1 - Funding Information: This work was supported by the NRF (2015R1A2A1A15053104, 2015R1D1A1A01056579 and 2016R1A5A1009405) through the National Research Foundation of Korea. The authors acknowledge PAL for beamline use (2015-first-2D-015 and 2015-second-2D-013). Publisher Copyright: © 2017 American Chemical Society.

PY - 2017/5/9

Y1 - 2017/5/9

N2 - Non-interpenetrated three-dimensional (3D) metal-organic frameworks (MOFs) with both an interpenetration-favorable (3,5)-c hms topology and an interpenetration-unfavorable (3,5)-c gra topology are converted to doubly interpenetrated analogues with hms-c topology by thermal treatment, even in the absence of solvent. Depending on the conversion temperature and the properties of the pillaring ligand in the non-interpenetrated 3D MOF, which is based on two-dimensional sheets with 3-c hcb topology pillared by neutral ditopic linkers, the pillaring ligands in the interpenetrated MOFs produced are partially removed during the thermal conversions, leading to interpenetrated MOFs that simultaneously contain both micro- and mesopores.

AB - Non-interpenetrated three-dimensional (3D) metal-organic frameworks (MOFs) with both an interpenetration-favorable (3,5)-c hms topology and an interpenetration-unfavorable (3,5)-c gra topology are converted to doubly interpenetrated analogues with hms-c topology by thermal treatment, even in the absence of solvent. Depending on the conversion temperature and the properties of the pillaring ligand in the non-interpenetrated 3D MOF, which is based on two-dimensional sheets with 3-c hcb topology pillared by neutral ditopic linkers, the pillaring ligands in the interpenetrated MOFs produced are partially removed during the thermal conversions, leading to interpenetrated MOFs that simultaneously contain both micro- and mesopores.

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Topology Conversions of Non-Interpenetrated Metal-Organic Frameworks to Doubly Interpenetrated Metal-Organic Frameworks

Abstract

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