Tight binding and fluorescent sensing of oxalate in water

Lijun Tang, Jinhee Park, Hae Jo Kim, Youngmee Kim, Jin Kim Sung, Jik Chin, Mook Kim Kwan

Research output: Contribution to journalArticlepeer-review

78 Scopus citations

Abstract

A dinuclear copper complex that binds tightly and selectively to oxalate over other dicarboxylates like malonate, succinate, and glutarate has been developed. This receptor can be used for fluorescent detection of oxalate in water at physicological pH by chemosensing ensemble approach. Crystal structure of oxalate bound to the receptor together with molecular mechanics and DFT computations provide insights into the tight and selective binding of the anion by the receptor.

Original languageEnglish
Pages (from-to)12606-12607
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number38
DOIs
StatePublished - 24 Sep 2008

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