Three-dimensional iron(ii) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

Jong Won Shin, Ah Rim Jeong, Sungeun Jeoung, Hoi Ri Moon, Yuki Komatsumaru, Shinya Hayami, Dohyun Moon, Kil Sik Min

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

We report a three-dimensional Fe(ii) porous coordination polymer that exhibits a spin crossover temperature change following CO2 sorption (though not N2 sorption). Furthermore, single crystals of the desolvated polymer with CO2 molecules at three different temperatures were characterised by X-ray crystallography.

Original languageEnglish
Pages (from-to)4262-4265
Number of pages4
JournalChemical Communications
Volume54
Issue number34
DOIs
StatePublished - 2018

Bibliographical note

Publisher Copyright:
© 2018 The Royal Society of Chemistry.

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