Three-dimensional framework containing Mn(salen)+ and Re6Se8(CN)64- cluster

Youngmee Kim, Seon Mi Park, Sung Jin Kim

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67 Scopus citations


Three-dimensional framework material containing Mn(salen)+ units and cyano-Re6Se8 clusters was prepared, and its crystal structure was determined by x-ray crystallography. The compound crystallized in the rhombohedral space group R3c with a = 16.1760(4) Å, c = 44.965(1) Å, V = 10189.3(4) Å3, and Z = 6. In the structure, each anionic cluster, Re6Se8(CN)64- was bridged by six Mn(salen)+ units to form a three-dimensional framework.

Original languageEnglish
Pages (from-to)592-595
Number of pages4
JournalInorganic Chemistry Communications
Issue number8
StatePublished - 2002

Bibliographical note

Funding Information:
This work was supported by the Korea Science & Engineering Foundation (R01-2000-000-00045-0 for S.-J. Kim and R03-2000-000-00002-0 for Y. Kim). We thank Dr. Alan J. Lough at the University of Toronto in Canada for the X-ray data collection and Dr. D.H. Shin in the Korea Basic Science Institute for the magnetic susceptibility measurements.


  • Cluster compounds
  • Cyanide complexes
  • Rhenium complexes
  • Three-dimensional framework


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