Three-dimensional framework containing Mn(salen)+ and Re6Se8(CN)64- cluster

Youngmee Kim; Seon Mi Park; Sung Jin Kim

doi:10.1016/S1387-7003(02)00484-7

Three-dimensional framework containing Mn(salen)⁺ and Re₆Se₈(CN)₆^4- cluster

Youngmee Kim, Seon Mi Park, Sung Jin Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

Three-dimensional framework material containing Mn(salen)⁺ units and cyano-Re₆Se₈ clusters was prepared, and its crystal structure was determined by x-ray crystallography. The compound crystallized in the rhombohedral space group R3c with a = 16.1760(4) Å, c = 44.965(1) Å, V = 10189.3(4) Å³, and Z = 6. In the structure, each anionic cluster, Re₆Se₈(CN)₆^4- was bridged by six Mn(salen)⁺ units to form a three-dimensional framework.

Original language	English
Pages (from-to)	592-595
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	5
Issue number	8
DOIs	https://doi.org/10.1016/S1387-7003(02)00484-7
State	Published - 2002

Bibliographical note

Funding Information:
This work was supported by the Korea Science & Engineering Foundation (R01-2000-000-00045-0 for S.-J. Kim and R03-2000-000-00002-0 for Y. Kim). We thank Dr. Alan J. Lough at the University of Toronto in Canada for the X-ray data collection and Dr. D.H. Shin in the Korea Basic Science Institute for the magnetic susceptibility measurements.

Keywords

Cluster compounds
Cyanide complexes
Rhenium complexes
Three-dimensional framework

Access to Document

10.1016/S1387-7003(02)00484-7

Cite this

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title = "Three-dimensional framework containing Mn(salen)+ and Re6Se8(CN)64- cluster",

abstract = "Three-dimensional framework material containing Mn(salen)+ units and cyano-Re6Se8 clusters was prepared, and its crystal structure was determined by x-ray crystallography. The compound crystallized in the rhombohedral space group R3c with a = 16.1760(4) {\AA}, c = 44.965(1) {\AA}, V = 10189.3(4) {\AA}3, and Z = 6. In the structure, each anionic cluster, Re6Se8(CN)64- was bridged by six Mn(salen)+ units to form a three-dimensional framework.",

keywords = "Cluster compounds, Cyanide complexes, Rhenium complexes, Three-dimensional framework",

author = "Youngmee Kim and Park, {Seon Mi} and Kim, {Sung Jin}",

note = "Funding Information: This work was supported by the Korea Science & Engineering Foundation (R01-2000-000-00045-0 for S.-J. Kim and R03-2000-000-00002-0 for Y. Kim). We thank Dr. Alan J. Lough at the University of Toronto in Canada for the X-ray data collection and Dr. D.H. Shin in the Korea Basic Science Institute for the magnetic susceptibility measurements.",

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doi = "10.1016/S1387-7003(02)00484-7",

language = "English",

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T1 - Three-dimensional framework containing Mn(salen)+ and Re6Se8(CN)64- cluster

AU - Kim, Youngmee

AU - Park, Seon Mi

AU - Kim, Sung Jin

N1 - Funding Information: This work was supported by the Korea Science & Engineering Foundation (R01-2000-000-00045-0 for S.-J. Kim and R03-2000-000-00002-0 for Y. Kim). We thank Dr. Alan J. Lough at the University of Toronto in Canada for the X-ray data collection and Dr. D.H. Shin in the Korea Basic Science Institute for the magnetic susceptibility measurements.

PY - 2002

Y1 - 2002

N2 - Three-dimensional framework material containing Mn(salen)+ units and cyano-Re6Se8 clusters was prepared, and its crystal structure was determined by x-ray crystallography. The compound crystallized in the rhombohedral space group R3c with a = 16.1760(4) Å, c = 44.965(1) Å, V = 10189.3(4) Å3, and Z = 6. In the structure, each anionic cluster, Re6Se8(CN)64- was bridged by six Mn(salen)+ units to form a three-dimensional framework.

AB - Three-dimensional framework material containing Mn(salen)+ units and cyano-Re6Se8 clusters was prepared, and its crystal structure was determined by x-ray crystallography. The compound crystallized in the rhombohedral space group R3c with a = 16.1760(4) Å, c = 44.965(1) Å, V = 10189.3(4) Å3, and Z = 6. In the structure, each anionic cluster, Re6Se8(CN)64- was bridged by six Mn(salen)+ units to form a three-dimensional framework.

KW - Cluster compounds

KW - Cyanide complexes

KW - Rhenium complexes

KW - Three-dimensional framework

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