Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions

Shunichi Fukuzumi; Ken Okamoto; Hiroshi Imahori

doi:10.1002/1521-3773(20020215)41:4<620::AID-ANIE620>3.0.CO;2-D

Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions

Shunichi Fukuzumi, Ken Okamoto, Hiroshi Imahori

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

Initiated by metal ions: Intramolecular electron transfer in a donor-acceptor linked system (a ferrocene-naphthoquinone dyad Fc-NQ; see scheme) can be started thermally by adding an appropriate metal ion (Sc³⁺) which can promote thermal electron transfer, which would otherwise be unlikely to occur, to give a radical ion complex (Fc⁺-NQ^·-/Sc³⁺).

Original language	English
Pages (from-to)	620-622
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	4
DOIs	https://doi.org/10.1002/1521-3773(20020215)41:4<620::AID-ANIE620>3.0.CO;2-D
State	Published - 15 Feb 2002

Keywords

Electron transfer
ESR
Ferrocene
Kinetics
Scandium

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10.1002/1521-3773(20020215)41:4<620::AID-ANIE620>3.0.CO;2-D

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AU - Fukuzumi, Shunichi

AU - Okamoto, Ken

AU - Imahori, Hiroshi

PY - 2002/2/15

Y1 - 2002/2/15

N2 - Initiated by metal ions: Intramolecular electron transfer in a donor-acceptor linked system (a ferrocene-naphthoquinone dyad Fc-NQ; see scheme) can be started thermally by adding an appropriate metal ion (Sc3+) which can promote thermal electron transfer, which would otherwise be unlikely to occur, to give a radical ion complex (Fc+-NQ·-/Sc3+).

AB - Initiated by metal ions: Intramolecular electron transfer in a donor-acceptor linked system (a ferrocene-naphthoquinone dyad Fc-NQ; see scheme) can be started thermally by adding an appropriate metal ion (Sc3+) which can promote thermal electron transfer, which would otherwise be unlikely to occur, to give a radical ion complex (Fc+-NQ·-/Sc3+).

KW - Electron transfer

KW - ESR

KW - Ferrocene

KW - Kinetics

KW - Scandium

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Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions

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Keywords

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