The HgCl2-promoted guanylation reaction: The scope and limitations

Catherine Levallet; Joanne Lerpiniere; Soo Y. Ko

doi:10.1016/S0040-4020(97)00193-2

The HgCl₂-promoted guanylation reaction: The scope and limitations

Catherine Levallet
, Joanne Lerpiniere
, Soo Y. Ko

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

136 Scopus citations

Abstract

The HgCl₂-promoted guanylation reaction was studied with various substituted thiourea starting materials and the scope and limitations are presented. The process was found to be effective with thioureas containing at least one N-conjugated substituent. Such activating groups include N-carbonyl-(acyl, alkoxycarbonyl, carbamoyl, etc.), N-cyano-, N-sulfonyl-, and N-aryl- substituents.

Original language	English
Pages (from-to)	5291-5304
Number of pages	14
Journal	Tetrahedron
Volume	53
Issue number	14
DOIs	https://doi.org/10.1016/S0040-4020(97)00193-2
State	Published - 7 Apr 1997

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title = "The HgCl2-promoted guanylation reaction: The scope and limitations",

abstract = "The HgCl2-promoted guanylation reaction was studied with various substituted thiourea starting materials and the scope and limitations are presented. The process was found to be effective with thioureas containing at least one N-conjugated substituent. Such activating groups include N-carbonyl-(acyl, alkoxycarbonyl, carbamoyl, etc.), N-cyano-, N-sulfonyl-, and N-aryl- substituents.",

author = "Catherine Levallet and Joanne Lerpiniere and Ko, \{Soo Y.\}",

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T2 - The scope and limitations

AU - Levallet, Catherine

AU - Lerpiniere, Joanne

AU - Ko, Soo Y.

PY - 1997/4/7

Y1 - 1997/4/7

N2 - The HgCl2-promoted guanylation reaction was studied with various substituted thiourea starting materials and the scope and limitations are presented. The process was found to be effective with thioureas containing at least one N-conjugated substituent. Such activating groups include N-carbonyl-(acyl, alkoxycarbonyl, carbamoyl, etc.), N-cyano-, N-sulfonyl-, and N-aryl- substituents.

AB - The HgCl2-promoted guanylation reaction was studied with various substituted thiourea starting materials and the scope and limitations are presented. The process was found to be effective with thioureas containing at least one N-conjugated substituent. Such activating groups include N-carbonyl-(acyl, alkoxycarbonyl, carbamoyl, etc.), N-cyano-, N-sulfonyl-, and N-aryl- substituents.

UR - https://www.scopus.com/pages/publications/0030936351

U2 - 10.1016/S0040-4020(97)00193-2

DO - 10.1016/S0040-4020(97)00193-2

M3 - Article

AN - SCOPUS:0030936351

SN - 0040-4020

VL - 53

SP - 5291

EP - 5304

JO - Tetrahedron

JF - Tetrahedron

IS - 14

ER -

The HgCl2-promoted guanylation reaction: The scope and limitations

Abstract

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The HgCl₂-promoted guanylation reaction: The scope and limitations