The frequency factor in statistical fullerene decay

K. Hansen; E. E.B. Campbell; O. Echt

doi:10.1016/j.ijms.2006.01.052

The frequency factor in statistical fullerene decay

K. Hansen, E. E.B. Campbell, O. Echt

Department of Physics

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Experiments on fullerene decay are reviewed and the frequency factor for C₂ emission is extracted. The value is also calculated theoretically. Inclusion of a number of previously disregarded degrees of freedom for the products increase the theoretical estimate for C₆₀ to above 10²⁰ s^-1, in good agreement with experimental results.

Original language	English
Pages (from-to)	79-95
Number of pages	17
Journal	International Journal of Mass Spectrometry
Volume	252
Issue number	2
DOIs	https://doi.org/10.1016/j.ijms.2006.01.052
State	Published - 15 May 2006

Keywords

Fullerene
Unimolecular decay

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10.1016/j.ijms.2006.01.052

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title = "The frequency factor in statistical fullerene decay",

abstract = "Experiments on fullerene decay are reviewed and the frequency factor for C2 emission is extracted. The value is also calculated theoretically. Inclusion of a number of previously disregarded degrees of freedom for the products increase the theoretical estimate for C60 to above 1020 s-1, in good agreement with experimental results.",

keywords = "Fullerene, Unimolecular decay",

author = "K. Hansen and Campbell, {E. E.B.} and O. Echt",

note = "Funding Information: This work has been supported by VR and EU via with Research and Training Network HPRN-CT-2000-00026. Many valuable discussions on the subject and comments on the manuscript by J.U. Andersen are gratefully acknowledged. ",

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AU - Campbell, E. E.B.

AU - Echt, O.

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PY - 2006/5/15

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N2 - Experiments on fullerene decay are reviewed and the frequency factor for C2 emission is extracted. The value is also calculated theoretically. Inclusion of a number of previously disregarded degrees of freedom for the products increase the theoretical estimate for C60 to above 1020 s-1, in good agreement with experimental results.

AB - Experiments on fullerene decay are reviewed and the frequency factor for C2 emission is extracted. The value is also calculated theoretically. Inclusion of a number of previously disregarded degrees of freedom for the products increase the theoretical estimate for C60 to above 1020 s-1, in good agreement with experimental results.

KW - Fullerene

KW - Unimolecular decay

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M3 - Article

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JO - International Journal of Mass Spectrometry

JF - International Journal of Mass Spectrometry

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ER -

The frequency factor in statistical fullerene decay

Abstract

Keywords

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