The first octahedral cluster complexes with terminal formate ligands: Synthesis, structure, and properties of K4[Re6S 8(HCOO)6] and Cs4[Re6S 8(HCOO)6]

Konstantin A. Brylev; Yuri V. Mironov; Svetlana G. Kozlova; Vladimir E. Fedorov; Sung Jin Kim; Hans Jürgen Pietzsch; Holger Stephan; Akitaka Ito; Shoji Ishizaka; Noboru Kitamura

doi:10.1021/ic802178q

The first octahedral cluster complexes with terminal formate ligands: Synthesis, structure, and properties of K₄[Re₆S ₈(HCOO)₆] and Cs₄[Re₆S ₈(HCOO)₆]

Konstantin A. Brylev
, Yuri V. Mironov
, Svetlana G. Kozlova
, Vladimir E. Fedorov
, Sung Jin Kim
, Hans Jürgen Pietzsch
, Holger Stephan
, Akitaka Ito
, Shoji Ishizaka
, Noboru Kitamura

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

The hexarhenium anionic cluster complex with terminal formate ligands [Re₆S₈(HCOO)₆]^4- was obtained by the room-temperature reaction between [Re₆S₈(OH) ₆]^4- and formic acid in an aqueous solution. The cluster was crystallized as a potassium or cesium salt and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV/vis, and luminescence spectroscopies. In particular, the emission quantum yield of the potassium salt of the Re₆ cluster anion in the solid phase was determined for the first time. The electronic structures of [Re ₆S₈(HCOO)₆]^4- and [Re ₆S₈(OH)₆]^4- were also elucidated by DFT calculations.

Original language	English
Pages (from-to)	2309-2315
Number of pages	7
Journal	Inorganic Chemistry
Volume	48
Issue number	5
DOIs	https://doi.org/10.1021/ic802178q
State	Published - 2 Mar 2009

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Brylev, K. A., Mironov, Y. V., Kozlova, S. G., Fedorov, V. E., Kim, S. J., Pietzsch, H. J., Stephan, H., Ito, A., Ishizaka, S., & Kitamura, N. (2009). The first octahedral cluster complexes with terminal formate ligands: Synthesis, structure, and properties of K₄[Re₆S ₈(HCOO)₆] and Cs₄[Re₆S ₈(HCOO)₆]. Inorganic Chemistry, 48(5), 2309-2315. https://doi.org/10.1021/ic802178q

@article{b794b12a1e944126a9a456f0e05cf86a,

title = "The first octahedral cluster complexes with terminal formate ligands: Synthesis, structure, and properties of K4[Re6S 8(HCOO)6] and Cs4[Re6S 8(HCOO)6]",

abstract = "The hexarhenium anionic cluster complex with terminal formate ligands [Re6S8(HCOO)6]4- was obtained by the room-temperature reaction between [Re6S8(OH) 6]4- and formic acid in an aqueous solution. The cluster was crystallized as a potassium or cesium salt and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV/vis, and luminescence spectroscopies. In particular, the emission quantum yield of the potassium salt of the Re6 cluster anion in the solid phase was determined for the first time. The electronic structures of [Re 6S8(HCOO)6]4- and [Re 6S8(OH)6]4- were also elucidated by DFT calculations.",

author = "Brylev, \{Konstantin A.\} and Mironov, \{Yuri V.\} and Kozlova, \{Svetlana G.\} and Fedorov, \{Vladimir E.\} and Kim, \{Sung Jin\} and Pietzsch, \{Hans J{\"u}rgen\} and Holger Stephan and Akitaka Ito and Shoji Ishizaka and Noboru Kitamura",

year = "2009",

month = mar,

day = "2",

doi = "10.1021/ic802178q",

language = "English",

volume = "48",

pages = "2309--2315",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - The first octahedral cluster complexes with terminal formate ligands

T2 - Synthesis, structure, and properties of K4[Re6S 8(HCOO)6] and Cs4[Re6S 8(HCOO)6]

AU - Brylev, Konstantin A.

AU - Mironov, Yuri V.

AU - Kozlova, Svetlana G.

AU - Fedorov, Vladimir E.

AU - Kim, Sung Jin

AU - Pietzsch, Hans Jürgen

AU - Stephan, Holger

AU - Ito, Akitaka

AU - Ishizaka, Shoji

AU - Kitamura, Noboru

PY - 2009/3/2

Y1 - 2009/3/2

N2 - The hexarhenium anionic cluster complex with terminal formate ligands [Re6S8(HCOO)6]4- was obtained by the room-temperature reaction between [Re6S8(OH) 6]4- and formic acid in an aqueous solution. The cluster was crystallized as a potassium or cesium salt and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV/vis, and luminescence spectroscopies. In particular, the emission quantum yield of the potassium salt of the Re6 cluster anion in the solid phase was determined for the first time. The electronic structures of [Re 6S8(HCOO)6]4- and [Re 6S8(OH)6]4- were also elucidated by DFT calculations.

AB - The hexarhenium anionic cluster complex with terminal formate ligands [Re6S8(HCOO)6]4- was obtained by the room-temperature reaction between [Re6S8(OH) 6]4- and formic acid in an aqueous solution. The cluster was crystallized as a potassium or cesium salt and characterized by X-ray single-crystal diffraction and elemental analyses, IR, 1H NMR, UV/vis, and luminescence spectroscopies. In particular, the emission quantum yield of the potassium salt of the Re6 cluster anion in the solid phase was determined for the first time. The electronic structures of [Re 6S8(HCOO)6]4- and [Re 6S8(OH)6]4- were also elucidated by DFT calculations.

UR - https://www.scopus.com/pages/publications/64549130461

U2 - 10.1021/ic802178q

DO - 10.1021/ic802178q

M3 - Article

C2 - 19159268

AN - SCOPUS:64549130461

SN - 0020-1669

VL - 48

SP - 2309

EP - 2315

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 5

ER -

The first octahedral cluster complexes with terminal formate ligands: Synthesis, structure, and properties of K4[Re6S 8(HCOO)6] and Cs4[Re6S 8(HCOO)6]

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The first octahedral cluster complexes with terminal formate ligands: Synthesis, structure, and properties of K₄[Re₆S ₈(HCOO)₆] and Cs₄[Re₆S ₈(HCOO)₆]