TY - JOUR
T1 - The first non-enzymatic reduction of acetaldehyde and analogues by an NADH model compound
AU - Ishikawa, Masashi
AU - Fukuzumi, Shunichi
PY - 1990
Y1 - 1990
N2 - An acid-stable NADH model compound, 9,10-dihydro-10-methylacridine (AcrH2) efficiently reduces acetaldehyde and analogues in the presence of HClO4 in acetonitrile to yield 10-methylacridinium ion and the corresponding alcohols; rates of the acid-catalysed reduction of various aliphatic aldehydes and ketones by AcrH2, which have small primary kinetic isotope effects (kH/kD < 2.0), are well correlated with those of the acid-catalysed electron transfer from the excited state of [Ru(bpy)3]2+ (bpy = 2,2′-bipyridine) to the same substrates.
AB - An acid-stable NADH model compound, 9,10-dihydro-10-methylacridine (AcrH2) efficiently reduces acetaldehyde and analogues in the presence of HClO4 in acetonitrile to yield 10-methylacridinium ion and the corresponding alcohols; rates of the acid-catalysed reduction of various aliphatic aldehydes and ketones by AcrH2, which have small primary kinetic isotope effects (kH/kD < 2.0), are well correlated with those of the acid-catalysed electron transfer from the excited state of [Ru(bpy)3]2+ (bpy = 2,2′-bipyridine) to the same substrates.
UR - http://www.scopus.com/inward/record.url?scp=0025113981&partnerID=8YFLogxK
U2 - 10.1039/C39900001353
DO - 10.1039/C39900001353
M3 - Article
AN - SCOPUS:0025113981
SN - 0022-4936
SP - 1353
EP - 1355
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 19
ER -