The first inorganic "tennis ball" encapsulating an anion

Kwan Mook Kim; Jung Su Park; Yeong Sang Kim; Yong Ju Jun; Tae Yi Kang; Youn Soo Sohn; Moo Jin Jun

doi:10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H

The first inorganic "tennis ball" encapsulating an anion

Kwan Mook Kim
, Jung Su Park
, Yeong Sang Kim
, Yong Ju Jun
, Tae Yi Kang
, Youn Soo Sohn
, Moo Jin Jun

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

New balls please! Reaction of Cu(BF₄)₂ with [(dach)Pt^II] (dach = trans (±)-1,2-diaminocyclohexane) and bis(ethylthio)methylenepropanedioate (BETMP) gave [{(dach)Pt(BETMP)}₂Cu(BF₄)₂] (1; shown schematically). Dimerization of 1 in methanol leads to the first inorganic "tennis ball" 2 [Eq. (1)]. A BF₄-ion is encapsulated in the cavity of 2.

Original language	English
Pages (from-to)	2458-2460
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	13
DOIs	https://doi.org/10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H
State	Published - 2 Jul 2001

Keywords

Anions
Host-guest systems
Self-assembly
Supramolecular chemistry

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10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H

Cite this

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title = "The first inorganic {"}tennis ball{"} encapsulating an anion",

abstract = "New balls please! Reaction of Cu(BF4)2 with [(dach)PtII] (dach = trans (±)-1,2-diaminocyclohexane) and bis(ethylthio)methylenepropanedioate (BETMP) gave [\{(dach)Pt(BETMP)\}2Cu(BF4)2] (1; shown schematically). Dimerization of 1 in methanol leads to the first inorganic {"}tennis ball{"} 2 [Eq. (1)]. A BF4-ion is encapsulated in the cavity of 2.",

keywords = "Anions, Host-guest systems, Self-assembly, Supramolecular chemistry",

author = "Kim, \{Kwan Mook\} and Park, \{Jung Su\} and Kim, \{Yeong Sang\} and Jun, \{Yong Ju\} and Kang, \{Tae Yi\} and Sohn, \{Youn Soo\} and Jun, \{Moo Jin\}",

year = "2001",

month = jul,

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doi = "10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H",

language = "English",

volume = "40",

pages = "2458--2460",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "13",

}

TY - JOUR

T1 - The first inorganic "tennis ball" encapsulating an anion

AU - Kim, Kwan Mook

AU - Park, Jung Su

AU - Kim, Yeong Sang

AU - Jun, Yong Ju

AU - Kang, Tae Yi

AU - Sohn, Youn Soo

AU - Jun, Moo Jin

PY - 2001/7/2

Y1 - 2001/7/2

N2 - New balls please! Reaction of Cu(BF4)2 with [(dach)PtII] (dach = trans (±)-1,2-diaminocyclohexane) and bis(ethylthio)methylenepropanedioate (BETMP) gave [{(dach)Pt(BETMP)}2Cu(BF4)2] (1; shown schematically). Dimerization of 1 in methanol leads to the first inorganic "tennis ball" 2 [Eq. (1)]. A BF4-ion is encapsulated in the cavity of 2.

AB - New balls please! Reaction of Cu(BF4)2 with [(dach)PtII] (dach = trans (±)-1,2-diaminocyclohexane) and bis(ethylthio)methylenepropanedioate (BETMP) gave [{(dach)Pt(BETMP)}2Cu(BF4)2] (1; shown schematically). Dimerization of 1 in methanol leads to the first inorganic "tennis ball" 2 [Eq. (1)]. A BF4-ion is encapsulated in the cavity of 2.

KW - Anions

KW - Host-guest systems

KW - Self-assembly

KW - Supramolecular chemistry

UR - https://www.scopus.com/pages/publications/0035796760

U2 - 10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H

DO - 10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H

M3 - Article

AN - SCOPUS:0035796760

SN - 1433-7851

VL - 40

SP - 2458

EP - 2460

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

The first inorganic "tennis ball" encapsulating an anion

Abstract

Keywords

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