The first inorganic "tennis ball" encapsulating an anion

Kwan Mook Kim; Jung Su Park; Yeong Sang Kim; Yong Ju Jun; Tae Yi Kang; Youn Soo Sohn; Moo Jin Jun

doi:10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H

The first inorganic "tennis ball" encapsulating an anion

Kwan Mook Kim, Jung Su Park, Yeong Sang Kim, Yong Ju Jun, Tae Yi Kang, Youn Soo Sohn, Moo Jin Jun

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

New balls please! Reaction of Cu(BF₄)₂ with [(dach)Pt^II] (dach = trans (±)-1,2-diaminocyclohexane) and bis(ethylthio)methylenepropanedioate (BETMP) gave [{(dach)Pt(BETMP)}₂Cu(BF₄)₂] (1; shown schematically). Dimerization of 1 in methanol leads to the first inorganic "tennis ball" 2 [Eq. (1)]. A BF₄-ion is encapsulated in the cavity of 2.

Original language	English
Pages (from-to)	2458-2460
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	13
DOIs	https://doi.org/10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H
State	Published - 2 Jul 2001

Keywords

Anions
Host-guest systems
Self-assembly
Supramolecular chemistry

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10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H

Cite this

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title = "The first inorganic {"}tennis ball{"} encapsulating an anion",

abstract = "New balls please! Reaction of Cu(BF4)2 with [(dach)PtII] (dach = trans (±)-1,2-diaminocyclohexane) and bis(ethylthio)methylenepropanedioate (BETMP) gave [{(dach)Pt(BETMP)}2Cu(BF4)2] (1; shown schematically). Dimerization of 1 in methanol leads to the first inorganic {"}tennis ball{"} 2 [Eq. (1)]. A BF4-ion is encapsulated in the cavity of 2.",

keywords = "Anions, Host-guest systems, Self-assembly, Supramolecular chemistry",

author = "Kim, {Kwan Mook} and Park, {Jung Su} and Kim, {Yeong Sang} and Jun, {Yong Ju} and Kang, {Tae Yi} and Sohn, {Youn Soo} and Jun, {Moo Jin}",

year = "2001",

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doi = "10.1002/1521-3773(20010702)40:13<2458::AID-ANIE2458>3.0.CO;2-H",

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T1 - The first inorganic "tennis ball" encapsulating an anion

AU - Kim, Kwan Mook

AU - Park, Jung Su

AU - Kim, Yeong Sang

AU - Jun, Yong Ju

AU - Kang, Tae Yi

AU - Sohn, Youn Soo

AU - Jun, Moo Jin

PY - 2001/7/2

Y1 - 2001/7/2

N2 - New balls please! Reaction of Cu(BF4)2 with [(dach)PtII] (dach = trans (±)-1,2-diaminocyclohexane) and bis(ethylthio)methylenepropanedioate (BETMP) gave [{(dach)Pt(BETMP)}2Cu(BF4)2] (1; shown schematically). Dimerization of 1 in methanol leads to the first inorganic "tennis ball" 2 [Eq. (1)]. A BF4-ion is encapsulated in the cavity of 2.

AB - New balls please! Reaction of Cu(BF4)2 with [(dach)PtII] (dach = trans (±)-1,2-diaminocyclohexane) and bis(ethylthio)methylenepropanedioate (BETMP) gave [{(dach)Pt(BETMP)}2Cu(BF4)2] (1; shown schematically). Dimerization of 1 in methanol leads to the first inorganic "tennis ball" 2 [Eq. (1)]. A BF4-ion is encapsulated in the cavity of 2.

KW - Anions

KW - Host-guest systems

KW - Self-assembly

KW - Supramolecular chemistry

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The first inorganic "tennis ball" encapsulating an anion

Abstract

Keywords

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