The first coordination polymers based on octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4- (Q = S, Se) and alkaline earth metal cations

Yuri V. Mironov; Vladimir E. Fedorov; Hyunjin Bang; Sung Jin Kim

doi:10.1002/ejic.200500738

The first coordination polymers based on octahedral hexahydroxo rhenium cluster complexes [Re₆Q₈(OH)₆]^4- (Q = S, Se) and alkaline earth metal cations

Yuri V. Mironov
, Vladimir E. Fedorov
, Hyunjin Bang
, Sung Jin Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Seven novel octahedral cluster compounds [{Mg(H₂O) ₅}₂-Re₆S₈(OH)₆] ·6H₂O (1), [{Ca(H₂O)₃} ₂Re₆S₈(OH)₆] (2), [{Ca-(H ₂O)₃}₂Re₆Se₈(OH) ₆] (3), [{Sr₂(H₂O)₁₀}Re ₆S₈(OH)₆]·6H₂O (4), [{Sr ₂(H₂O)₁₀}Re₆Se₈(OH) ₆]·6H₂O (5), [{Ba₂(H₂O) ₈}-Re₆S₈(OH)₆] (6), and [{Ba ₂(H₂O)₈}Re₆Se₈(OH) ₆] (7) were prepared by the direct reaction of K₄[Re ₆S₈(OH)₆]·8H₂O and K ₄[Re₆Se₈(OH)₆]·8H ₂O with the cations of the elements of main group II. All compounds have been characterized by single crystal X-ray diffraction. Compound 1 has a discrete molecular structure, compounds 4 and 5 have a one-dimensional chain structure, and compounds 2, 3, 6, and 7 crystallize in two different types of two-dimensional layered structure. This sulfur containing series has been characterized by luminescent spectroscopy.

Original language	English
Pages (from-to)	553-557
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Issue number	3
DOIs	https://doi.org/10.1002/ejic.200500738
State	Published - 6 Feb 2006

Keywords

Cluster compounds
Luminescent properties
Rhenium
Synthesis

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10.1002/ejic.200500738

Cite this

@article{9067a0a17dfc4b78b7edd7d5bc5b52d9,

title = "The first coordination polymers based on octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4- (Q = S, Se) and alkaline earth metal cations",

abstract = "Seven novel octahedral cluster compounds [\{Mg(H2O) 5\}2-Re6S8(OH)6] ·6H2O (1), [\{Ca(H2O)3\} 2Re6S8(OH)6] (2), [\{Ca-(H 2O)3\}2Re6Se8(OH) 6] (3), [\{Sr2(H2O)10\}Re 6S8(OH)6]·6H2O (4), [\{Sr 2(H2O)10\}Re6Se8(OH) 6]·6H2O (5), [\{Ba2(H2O) 8\}-Re6S8(OH)6] (6), and [\{Ba 2(H2O)8\}Re6Se8(OH) 6] (7) were prepared by the direct reaction of K4[Re 6S8(OH)6]·8H2O and K 4[Re6Se8(OH)6]·8H 2O with the cations of the elements of main group II. All compounds have been characterized by single crystal X-ray diffraction. Compound 1 has a discrete molecular structure, compounds 4 and 5 have a one-dimensional chain structure, and compounds 2, 3, 6, and 7 crystallize in two different types of two-dimensional layered structure. This sulfur containing series has been characterized by luminescent spectroscopy.",

keywords = "Cluster compounds, Luminescent properties, Rhenium, Synthesis",

author = "Mironov, \{Yuri V.\} and Fedorov, \{Vladimir E.\} and Hyunjin Bang and Kim, \{Sung Jin\}",

year = "2006",

month = feb,

day = "6",

doi = "10.1002/ejic.200500738",

language = "English",

pages = "553--557",

journal = "European Journal of Inorganic Chemistry",

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TY - JOUR

T1 - The first coordination polymers based on octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4- (Q = S, Se) and alkaline earth metal cations

AU - Mironov, Yuri V.

AU - Fedorov, Vladimir E.

AU - Bang, Hyunjin

AU - Kim, Sung Jin

PY - 2006/2/6

Y1 - 2006/2/6

N2 - Seven novel octahedral cluster compounds [{Mg(H2O) 5}2-Re6S8(OH)6] ·6H2O (1), [{Ca(H2O)3} 2Re6S8(OH)6] (2), [{Ca-(H 2O)3}2Re6Se8(OH) 6] (3), [{Sr2(H2O)10}Re 6S8(OH)6]·6H2O (4), [{Sr 2(H2O)10}Re6Se8(OH) 6]·6H2O (5), [{Ba2(H2O) 8}-Re6S8(OH)6] (6), and [{Ba 2(H2O)8}Re6Se8(OH) 6] (7) were prepared by the direct reaction of K4[Re 6S8(OH)6]·8H2O and K 4[Re6Se8(OH)6]·8H 2O with the cations of the elements of main group II. All compounds have been characterized by single crystal X-ray diffraction. Compound 1 has a discrete molecular structure, compounds 4 and 5 have a one-dimensional chain structure, and compounds 2, 3, 6, and 7 crystallize in two different types of two-dimensional layered structure. This sulfur containing series has been characterized by luminescent spectroscopy.

AB - Seven novel octahedral cluster compounds [{Mg(H2O) 5}2-Re6S8(OH)6] ·6H2O (1), [{Ca(H2O)3} 2Re6S8(OH)6] (2), [{Ca-(H 2O)3}2Re6Se8(OH) 6] (3), [{Sr2(H2O)10}Re 6S8(OH)6]·6H2O (4), [{Sr 2(H2O)10}Re6Se8(OH) 6]·6H2O (5), [{Ba2(H2O) 8}-Re6S8(OH)6] (6), and [{Ba 2(H2O)8}Re6Se8(OH) 6] (7) were prepared by the direct reaction of K4[Re 6S8(OH)6]·8H2O and K 4[Re6Se8(OH)6]·8H 2O with the cations of the elements of main group II. All compounds have been characterized by single crystal X-ray diffraction. Compound 1 has a discrete molecular structure, compounds 4 and 5 have a one-dimensional chain structure, and compounds 2, 3, 6, and 7 crystallize in two different types of two-dimensional layered structure. This sulfur containing series has been characterized by luminescent spectroscopy.

KW - Cluster compounds

KW - Luminescent properties

KW - Rhenium

KW - Synthesis

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DO - 10.1002/ejic.200500738

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