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Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): A multi-electron donor system subject to conformational control

  • Atanu Jana
  • , Masatoshi Ishida
  • , Kevin Cho
  • , Sudip Kumar Ghosh
  • , Kyuju Kwak
  • , Kei Ohkubo
  • , Young Mo Sung
  • , Christina M. Davis
  • , Vincent M. Lynch
  • , Dongil Lee
  • , Shunichi Fukuzumi
  • , Dongho Kim
  • , Jonathan L. Sessler

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible π-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexakis-TTF annulated hexaphyrin, was analyzed.

Original languageEnglish
Pages (from-to)8937-8939
Number of pages3
JournalChemical Communications
Volume49
Issue number79
DOIs
StatePublished - 10 Sep 2013

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