Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): A multi-electron donor system subject to conformational control

Atanu Jana, Masatoshi Ishida, Kevin Cho, Sudip Kumar Ghosh, Kyuju Kwak, Kei Ohkubo, Young Mo Sung, Christina M. Davis, Vincent M. Lynch, Dongil Lee, Shunichi Fukuzumi, Dongho Kim, Jonathan L. Sessler

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible π-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexakis-TTF annulated hexaphyrin, was analyzed.

Original languageEnglish
Pages (from-to)8937-8939
Number of pages3
JournalChemical Communications
Volume49
Issue number79
DOIs
StatePublished - 10 Sep 2013

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