TY - JOUR
T1 - Tetra-ethyl-ammonium dichlorido[N,N′-(o-phenyl-ene)bis-(isoquinoline- 2-carboxamidato)-4 N]cobaltate(III)
AU - Lee, Do Nam
AU - Lee, Eun Yong
AU - Kim, Cheal
AU - Kim, Sung Jin
AU - Kim, Youngmee
PY - 2007/6/6
Y1 - 2007/6/6
N2 - In the title compound, (C8H20N)[Co(C26H16N4O2)Cl2], the four N atoms of the N,N′-(o-phenyl-ene)bis-(isoquinoline-2-carboxamidate) (biqb2-) ligand form the equatorial plane of a distorted octa-hedral coordination environment around the CoIII ion, while two chloride ligands are axially coordinated. The Co - Namide distances are significantly shorter than the Co - Npyrid-yl distances. The dihedral angle between the two isoquinoline fused-ring systems is 25.72 (7)°. The crystal structure is stabilized, in part, by inter-molecular Ccation - H⋯Cl and Cisoquinoline - H⋯Cl hydrogen bonds.
AB - In the title compound, (C8H20N)[Co(C26H16N4O2)Cl2], the four N atoms of the N,N′-(o-phenyl-ene)bis-(isoquinoline-2-carboxamidate) (biqb2-) ligand form the equatorial plane of a distorted octa-hedral coordination environment around the CoIII ion, while two chloride ligands are axially coordinated. The Co - Namide distances are significantly shorter than the Co - Npyrid-yl distances. The dihedral angle between the two isoquinoline fused-ring systems is 25.72 (7)°. The crystal structure is stabilized, in part, by inter-molecular Ccation - H⋯Cl and Cisoquinoline - H⋯Cl hydrogen bonds.
UR - http://www.scopus.com/inward/record.url?scp=34547212991&partnerID=8YFLogxK
U2 - 10.1107/S1600536807029091
DO - 10.1107/S1600536807029091
M3 - Article
AN - SCOPUS:34547212991
SN - 1600-5368
VL - 63
SP - m1949-m1950
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -