Tetra-μ-benzoato-bis[(quinoxaline)copper(II)]

Eun Yong Lee; Byeong Kwon Park; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1107/S1600536807067876

Tetra-μ-benzoato-bis[(quinoxaline)copper(II)]

Eun Yong Lee, Byeong Kwon Park, Cheal Kim, Sung Jin Kim, Youngmee Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The paddlewheel-type centrosymmetric dinuclear title complex, [Cu2(C7H5O2)4(C8H6N2)2], contains four bridging benzoate groups and two terminal quinoxaline ligands. The octa-hedral coordination around each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a quinoxaline mol-ecule [Cu - N = 2.2465 (18) Å] and by the second Cu atom [Cu⋯Cu = 2.668 (5) Å]. The Cu atom is 0.216 Å out of the plane of the four O atoms.

Original language	English
Pages (from-to)	m286
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	2
DOIs	https://doi.org/10.1107/S1600536807067876
State	Published - 2008

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title = "Tetra-μ-benzoato-bis[(quinoxaline)copper(II)]",

abstract = "The paddlewheel-type centrosymmetric dinuclear title complex, [Cu2(C7H5O2)4(C8H6N2)2], contains four bridging benzoate groups and two terminal quinoxaline ligands. The octa-hedral coordination around each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a quinoxaline mol-ecule [Cu - N = 2.2465 (18) {\AA}] and by the second Cu atom [Cu⋯Cu = 2.668 (5) {\AA}]. The Cu atom is 0.216 {\AA} out of the plane of the four O atoms.",

author = "Lee, {Eun Yong} and Park, {Byeong Kwon} and Cheal Kim and Kim, {Sung Jin} and Youngmee Kim",

year = "2008",

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T1 - Tetra-μ-benzoato-bis[(quinoxaline)copper(II)]

AU - Lee, Eun Yong

AU - Park, Byeong Kwon

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

PY - 2008

Y1 - 2008

N2 - The paddlewheel-type centrosymmetric dinuclear title complex, [Cu2(C7H5O2)4(C8H6N2)2], contains four bridging benzoate groups and two terminal quinoxaline ligands. The octa-hedral coordination around each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a quinoxaline mol-ecule [Cu - N = 2.2465 (18) Å] and by the second Cu atom [Cu⋯Cu = 2.668 (5) Å]. The Cu atom is 0.216 Å out of the plane of the four O atoms.

AB - The paddlewheel-type centrosymmetric dinuclear title complex, [Cu2(C7H5O2)4(C8H6N2)2], contains four bridging benzoate groups and two terminal quinoxaline ligands. The octa-hedral coordination around each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a quinoxaline mol-ecule [Cu - N = 2.2465 (18) Å] and by the second Cu atom [Cu⋯Cu = 2.668 (5) Å]. The Cu atom is 0.216 Å out of the plane of the four O atoms.

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U2 - 10.1107/S1600536807067876

DO - 10.1107/S1600536807067876

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SN - 1600-5368

VL - 64

SP - m286

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

Tetra-μ-benzoato-bis[(quinoxaline)copper(II)]

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