Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides

W. Nam; S. Y. Oh; Hee Lim Mi Hee Lim; M. H. Choi; S. Y. Han; G. J. Jhon

doi:10.1039/b005162o

Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides

W. Nam, S. Y. Oh, Hee Lim Mi Hee Lim, M. H. Choi, S. Y. Han, G. J. Jhon

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

An electron-deficient iron porphyrin complex catalyzes the epoxidation of olefins by tert-alkyl hydroperoxides via radical-free oxidation reactions in aprotic solvent; the epoxidation reactions were markedly influenced by reaction temperature and high yields of epoxide products were obtained with retention of stereospecificity at low temperature.

Original language	English
Pages (from-to)	1787-1788
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/b005162o
State	Published - 21 Sep 2000

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title = "Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides",

abstract = "An electron-deficient iron porphyrin complex catalyzes the epoxidation of olefins by tert-alkyl hydroperoxides via radical-free oxidation reactions in aprotic solvent; the epoxidation reactions were markedly influenced by reaction temperature and high yields of epoxide products were obtained with retention of stereospecificity at low temperature.",

author = "W. Nam and Oh, {S. Y.} and {Mi Hee Lim}, {Hee Lim} and Choi, {M. H.} and Han, {S. Y.} and Jhon, {G. J.}",

year = "2000",

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day = "21",

doi = "10.1039/b005162o",

language = "English",

pages = "1787--1788",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides

AU - Nam, W.

AU - Oh, S. Y.

AU - Mi Hee Lim, Hee Lim

AU - Choi, M. H.

AU - Han, S. Y.

AU - Jhon, G. J.

PY - 2000/9/21

Y1 - 2000/9/21

N2 - An electron-deficient iron porphyrin complex catalyzes the epoxidation of olefins by tert-alkyl hydroperoxides via radical-free oxidation reactions in aprotic solvent; the epoxidation reactions were markedly influenced by reaction temperature and high yields of epoxide products were obtained with retention of stereospecificity at low temperature.

AB - An electron-deficient iron porphyrin complex catalyzes the epoxidation of olefins by tert-alkyl hydroperoxides via radical-free oxidation reactions in aprotic solvent; the epoxidation reactions were markedly influenced by reaction temperature and high yields of epoxide products were obtained with retention of stereospecificity at low temperature.

UR - http://www.scopus.com/inward/record.url?scp=0034699422&partnerID=8YFLogxK

U2 - 10.1039/b005162o

DO - 10.1039/b005162o

M3 - Article

AN - SCOPUS:0034699422

SN - 1359-7345

SP - 1787

EP - 1788

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides

Abstract

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