Synthetic applications of the cyclic iminocarbonate rearrangement Enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone

Jung Nam Park; Soo Y. Ko; Hun Y. Koh

doi:10.1016/S0040-4039(00)00878-9

Synthetic applications of the cyclic iminocarbonate rearrangement Enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone

Jung Nam Park, Soo Y. Ko, Hun Y. Koh

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

Chloramphenicol and 4-epi-cytoxazone have been enantioselectively synthesized using the asymmetric dihydroxylation and the cyclic iminocarbonate rearrangement as key steps. (C) 2000 Elsevier Science Ltd.

Original language	English
Pages (from-to)	5553-5556
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	29
DOIs	https://doi.org/10.1016/S0040-4039(00)00878-9
State	Published - 15 Jul 2000

Bibliographical note

Funding Information:
This work was supported by the MOST through the National R&D Program for Women's Universities (Project No. 99-N6-01-01-A-08), and by the KOSEF (1999-2-122-002-4). J.N.P. is grateful to the Brain Korea 21 project for a graduate fellowship.

Keywords

4-epi-cytoxazone
Chloramphenicol
Cyclic iminocarbonate rearrangement
Enantioselective synthesis
Regioselection

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10.1016/S0040-4039(00)00878-9

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title = "Synthetic applications of the cyclic iminocarbonate rearrangement Enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone",

abstract = "Chloramphenicol and 4-epi-cytoxazone have been enantioselectively synthesized using the asymmetric dihydroxylation and the cyclic iminocarbonate rearrangement as key steps. (C) 2000 Elsevier Science Ltd.",

keywords = "4-epi-cytoxazone, Chloramphenicol, Cyclic iminocarbonate rearrangement, Enantioselective synthesis, Regioselection",

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note = "Funding Information: This work was supported by the MOST through the National R&D Program for Women's Universities (Project No. 99-N6-01-01-A-08), and by the KOSEF (1999-2-122-002-4). J.N.P. is grateful to the Brain Korea 21 project for a graduate fellowship.",

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AU - Park, Jung Nam

AU - Ko, Soo Y.

AU - Koh, Hun Y.

N1 - Funding Information: This work was supported by the MOST through the National R&D Program for Women's Universities (Project No. 99-N6-01-01-A-08), and by the KOSEF (1999-2-122-002-4). J.N.P. is grateful to the Brain Korea 21 project for a graduate fellowship.

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Y1 - 2000/7/15

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AB - Chloramphenicol and 4-epi-cytoxazone have been enantioselectively synthesized using the asymmetric dihydroxylation and the cyclic iminocarbonate rearrangement as key steps. (C) 2000 Elsevier Science Ltd.

KW - 4-epi-cytoxazone

KW - Chloramphenicol

KW - Cyclic iminocarbonate rearrangement

KW - Enantioselective synthesis

KW - Regioselection

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IS - 29

ER -

Synthetic applications of the cyclic iminocarbonate rearrangement Enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone

Abstract

Bibliographical note

Keywords

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