Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO4)2

V. V. Atuchin; O. D. Chimitova; T. A. Gavrilova; M. S. Molokeev; Sung Jin Kim; N. V. Surovtsev; B. G. Bazarov

doi:10.1016/j.jcrysgro.2010.09.076

Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO₄)₂

V. V. Atuchin, O. D. Chimitova, T. A. Gavrilova, M. S. Molokeev, Sung Jin Kim, N. V. Surovtsev, B. G. Bazarov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

97 Scopus citations

Abstract

Rubidium neodymium dimolybdate, RbNd(MoO₄)₂, microcrystals have been fabricated by solid state synthesis at T=550600°C by t=324 ks. Crystal structure of RbNd(MoO₄)₂ has been refined by Rietveld method in space group Pbcn with cell parameters a=5.1772(1) Å, b=18.7293(4) Å, and c=8.2774(1) Å (R_B=5.05%). The crystal structure of RbNd(MoO₄)₂ consists of layers of MoO₄ tetrahedrons corner-sharing with NdO₈ square antiprisms. These layers are perpendicular to b-axis of the unit cell. About 20 narrow Raman lines have been observed in Raman spectrum recorded for RbNd(MoO₄)₂ powder sample.

Original language	English
Pages (from-to)	683-686
Number of pages	4
Journal	Journal of Crystal Growth
Volume	318
Issue number	1
DOIs	https://doi.org/10.1016/j.jcrysgro.2010.09.076
State	Published - 1 Mar 2011

Bibliographical note

Funding Information:
This study was partly supported by SB RAS (Grant 34 ).

Keywords

A1. Crystal structure
A2. Solid state synthesis
B1. Molybdate

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10.1016/j.jcrysgro.2010.09.076

Cite this

@article{9b0d2bf91234490892a4725e5ef22ed8,

title = "Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO4)2",

abstract = "Rubidium neodymium dimolybdate, RbNd(MoO4)2, microcrystals have been fabricated by solid state synthesis at T=550600°C by t=324 ks. Crystal structure of RbNd(MoO4)2 has been refined by Rietveld method in space group Pbcn with cell parameters a=5.1772(1) {\AA}, b=18.7293(4) {\AA}, and c=8.2774(1) {\AA} (RB=5.05%). The crystal structure of RbNd(MoO4)2 consists of layers of MoO4 tetrahedrons corner-sharing with NdO8 square antiprisms. These layers are perpendicular to b-axis of the unit cell. About 20 narrow Raman lines have been observed in Raman spectrum recorded for RbNd(MoO4)2 powder sample.",

keywords = "A1. Crystal structure, A2. Solid state synthesis, B1. Molybdate",

author = "Atuchin, {V. V.} and Chimitova, {O. D.} and Gavrilova, {T. A.} and Molokeev, {M. S.} and Kim, {Sung Jin} and Surovtsev, {N. V.} and Bazarov, {B. G.}",

note = "Funding Information: This study was partly supported by SB RAS (Grant 34 ).",

year = "2011",

month = mar,

day = "1",

doi = "10.1016/j.jcrysgro.2010.09.076",

language = "English",

volume = "318",

pages = "683--686",

journal = "Journal of Crystal Growth",

issn = "0022-0248",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO4)2

AU - Atuchin, V. V.

AU - Chimitova, O. D.

AU - Gavrilova, T. A.

AU - Molokeev, M. S.

AU - Kim, Sung Jin

AU - Surovtsev, N. V.

AU - Bazarov, B. G.

N1 - Funding Information: This study was partly supported by SB RAS (Grant 34 ).

PY - 2011/3/1

Y1 - 2011/3/1

N2 - Rubidium neodymium dimolybdate, RbNd(MoO4)2, microcrystals have been fabricated by solid state synthesis at T=550600°C by t=324 ks. Crystal structure of RbNd(MoO4)2 has been refined by Rietveld method in space group Pbcn with cell parameters a=5.1772(1) Å, b=18.7293(4) Å, and c=8.2774(1) Å (RB=5.05%). The crystal structure of RbNd(MoO4)2 consists of layers of MoO4 tetrahedrons corner-sharing with NdO8 square antiprisms. These layers are perpendicular to b-axis of the unit cell. About 20 narrow Raman lines have been observed in Raman spectrum recorded for RbNd(MoO4)2 powder sample.

AB - Rubidium neodymium dimolybdate, RbNd(MoO4)2, microcrystals have been fabricated by solid state synthesis at T=550600°C by t=324 ks. Crystal structure of RbNd(MoO4)2 has been refined by Rietveld method in space group Pbcn with cell parameters a=5.1772(1) Å, b=18.7293(4) Å, and c=8.2774(1) Å (RB=5.05%). The crystal structure of RbNd(MoO4)2 consists of layers of MoO4 tetrahedrons corner-sharing with NdO8 square antiprisms. These layers are perpendicular to b-axis of the unit cell. About 20 narrow Raman lines have been observed in Raman spectrum recorded for RbNd(MoO4)2 powder sample.

KW - A1. Crystal structure

KW - A2. Solid state synthesis

KW - B1. Molybdate

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DO - 10.1016/j.jcrysgro.2010.09.076

M3 - Article

AN - SCOPUS:79952738962

SN - 0022-0248

VL - 318

SP - 683

EP - 686

JO - Journal of Crystal Growth

JF - Journal of Crystal Growth

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