Synthesis of zirconium-based metal-organic framework/gelatin aerogel for removing phosphate and fluoride from aqueous solutions

This study describes the preparation of novel hybrid aerogels derived from gelatin (Gel), incorporating Br-functionalized zirconium-based metal-organic framework (UiO-66-Br; MOF) as modifying agent to effectively eliminate phosphate and fluoride ions from aqueous environments. The adsorption performance of MOF decorated Gel (Gel-xMOF) hybrid aerogels was investigated under different conditions, including agitation time, adsorbent dosage, solution pH, initial phosphate and fluoride concentrations, coexisting ions, and temperature. The functional groups of the gelatin network, coupled with UiO-66-Br, enhanced the adsorption performance of phosphate and fluoride ions from aqueous solutions. The structural features and physicochemical parameters were evaluated using several characterization tools. The mesoporous Gel-1.5MOF aerogels exhibited Langmuir adsorption capacities of 20.8 and 7.42 mg/g for phosphate and fluoride, respectively. Reusability and coexisting experiment results suggest that the as-prepared Gel-1.5MOF aerogels have the potential for practical applications. Electrostatic attraction and ligand exchange primarily govern the adsorption mechanism of both ions, followed by hydrogen bonding and pore-filling mechanisms. This investigation offers new insights into the successful elimination of phosphate and fluoride ions across a broad pH range.