Synthesis of Highly Crystalline Single-Phase CoNb2O6 Nanofibers at Low Temperature and Their Structural Characterizations

Joohee Park, Song Hee Lee, Soungmin Bae, Myung Hwa Kim, Seokhyun Yoon

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

We report the synthesis of highly crystalline single-phase CoNb2O6 nanofibers using an electrospinning method. Columbite niobate compounds (ANb2O6, A = Ca2+, Mg2+, Zn2+, Ni2+, Sn2+, and Co2+) are promising ceramic materials for many potential applications such as microwave devices and photocatalysts operating at room temperature. The fundamental characteristics including structural and electronic properties at room temperature, however, are not extensively studied at the moment. By combining the basic characterization utilizing electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, and the first principles approach, we reveal the fundamental correlation between the lattice structure and the electronic structure of CoNb2O6. Our approach can readily be extended to studying other families of niobate ceramics made on the nanoscale for room-temperature applications.

Original languageEnglish
Pages (from-to)4395-4400
Number of pages6
JournalCrystal Growth and Design
Volume23
Issue number6
DOIs
StatePublished - 7 Jun 2023

Bibliographical note

Funding Information:
This work was supported by the Basic Science Research Program (NRF-2018R1A6A1A03025340, NRF-2022R1A2C1010497, and NRF-2021R1F1A1053270) through the National Research Foundation of Korea (NRF). S.B. was supported by a Grant-in-Aid for JSPS Fellows (No. 202115353). The authors thank the Research Center for Computational Science at ISSP and Information Technology Center at the University of Tokyo for generous computing resources.

Publisher Copyright:
© 2023 American Chemical Society

Fingerprint

Dive into the research topics of 'Synthesis of Highly Crystalline Single-Phase CoNb2O6 Nanofibers at Low Temperature and Their Structural Characterizations'. Together they form a unique fingerprint.

Cite this