Synthesis and structure of novel coordination compounds based on [Re 6Q8(CN)6]4- (Q = S, Se) and (SnMe3)+

M. S. Tarasenko; A. Yu Ledneva; N. V. Kurat'eva; D. Yu Naumov; Sung Jin Kim; V. E. Fedorov; N. G. Naumov

doi:10.1134/S1070328407120020

Synthesis and structure of novel coordination compounds based on [Re ₆Q₈(CN)₆]^4- (Q = S, Se) and (SnMe₃)⁺

M. S. Tarasenko, A. Yu Ledneva, N. V. Kurat'eva, D. Yu Naumov, Sung Jin Kim, V. E. Fedorov, N. G. Naumov

Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The reactions of SnMe₃Cl with salts of the cluster anionic complexes [Re₆Q₈(CN)₆]^4- (Q = S, Se) gave novel complexes [{(SnMe₃)₂(OH)} ₂{SnMe₃}₂{Re₆S₈(CN) ₆}] (I), (Me₄N)₂[{SnMe₃(H ₂O)}₂{Re₆Se₈(CN)₆}] (II), [{(SnMe₂)₄(μ₃-O)}₂{Re ₆Se₈(CN)₆}] (III), and [(SnMe₂) ₄(μ₃-O)₂(μ₂-OH) ₂(H₂O)₂][{SnMe₃ ₂{Re ₆Se₈(CN)₆}] (IV). The structures of I-IV were determined by X-ray diffraction. Compounds I, IV have the chain structures with the CN-SnMe₃-NC bridges between the cluster anions [Re ₆Q₈(CN)₆]^4-. Compound II contains isolated fragments {SnMe₃(H₂O)}₂{Re ₆Se₈(CN)₆}^2-. In the polymer framework of compound III, the cluster anionic complexes [Re₆Se ₈(CN)₆]^4- are bound by the complex cations [(SnMe₂)₄(μ₃-O)₂]⁴⁺ formed due to the hydrolysis of the initial (SnMe₃)Cl.

Original language	English
Pages (from-to)	876-885
Number of pages	10
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	33
Issue number	12
DOIs	https://doi.org/10.1134/S1070328407120020
State	Published - Dec 2007

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@article{d1135a99323f451193babefb975ed51f,

title = "Synthesis and structure of novel coordination compounds based on [Re 6Q8(CN)6]4- (Q = S, Se) and (SnMe3)+",

abstract = "The reactions of SnMe3Cl with salts of the cluster anionic complexes [Re6Q8(CN)6]4- (Q = S, Se) gave novel complexes [{(SnMe3)2(OH)} 2{SnMe3}2{Re6S8(CN) 6}] (I), (Me4N)2[{SnMe3(H 2O)}2{Re6Se8(CN)6}] (II), [{(SnMe2)4(μ3-O)}2{Re 6Se8(CN)6}] (III), and [(SnMe2) 4(μ3-O)2(μ2-OH) 2(H2O)2][{SnMe3 2{Re 6Se8(CN)6}] (IV). The structures of I-IV were determined by X-ray diffraction. Compounds I, IV have the chain structures with the CN-SnMe3-NC bridges between the cluster anions [Re 6Q8(CN)6]4-. Compound II contains isolated fragments {SnMe3(H2O)}2{Re 6Se8(CN)6}2-. In the polymer framework of compound III, the cluster anionic complexes [Re6Se 8(CN)6]4- are bound by the complex cations [(SnMe2)4(μ3-O)2]4+ formed due to the hydrolysis of the initial (SnMe3)Cl.",

author = "Tarasenko, {M. S.} and Ledneva, {A. Yu} and Kurat'eva, {N. V.} and Naumov, {D. Yu} and Kim, {Sung Jin} and Fedorov, {V. E.} and Naumov, {N. G.}",

note = "Funding Information: ACKNOWLEDGMENTS This work was fulfilled in the framework of the state contract no. 02.442.117414 and supported by the FCSTP program “The studies and developments in the priority directions of science and technology in 2002– 2006”.",

year = "2007",

month = dec,

doi = "10.1134/S1070328407120020",

language = "English",

volume = "33",

pages = "876--885",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Pleiades Publishing",

number = "12",

}

TY - JOUR

T1 - Synthesis and structure of novel coordination compounds based on [Re 6Q8(CN)6]4- (Q = S, Se) and (SnMe3)+

AU - Tarasenko, M. S.

AU - Ledneva, A. Yu

AU - Kurat'eva, N. V.

AU - Naumov, D. Yu

AU - Kim, Sung Jin

AU - Fedorov, V. E.

AU - Naumov, N. G.

N1 - Funding Information: ACKNOWLEDGMENTS This work was fulfilled in the framework of the state contract no. 02.442.117414 and supported by the FCSTP program “The studies and developments in the priority directions of science and technology in 2002– 2006”.

PY - 2007/12

Y1 - 2007/12

N2 - The reactions of SnMe3Cl with salts of the cluster anionic complexes [Re6Q8(CN)6]4- (Q = S, Se) gave novel complexes [{(SnMe3)2(OH)} 2{SnMe3}2{Re6S8(CN) 6}] (I), (Me4N)2[{SnMe3(H 2O)}2{Re6Se8(CN)6}] (II), [{(SnMe2)4(μ3-O)}2{Re 6Se8(CN)6}] (III), and [(SnMe2) 4(μ3-O)2(μ2-OH) 2(H2O)2][{SnMe3 2{Re 6Se8(CN)6}] (IV). The structures of I-IV were determined by X-ray diffraction. Compounds I, IV have the chain structures with the CN-SnMe3-NC bridges between the cluster anions [Re 6Q8(CN)6]4-. Compound II contains isolated fragments {SnMe3(H2O)}2{Re 6Se8(CN)6}2-. In the polymer framework of compound III, the cluster anionic complexes [Re6Se 8(CN)6]4- are bound by the complex cations [(SnMe2)4(μ3-O)2]4+ formed due to the hydrolysis of the initial (SnMe3)Cl.

AB - The reactions of SnMe3Cl with salts of the cluster anionic complexes [Re6Q8(CN)6]4- (Q = S, Se) gave novel complexes [{(SnMe3)2(OH)} 2{SnMe3}2{Re6S8(CN) 6}] (I), (Me4N)2[{SnMe3(H 2O)}2{Re6Se8(CN)6}] (II), [{(SnMe2)4(μ3-O)}2{Re 6Se8(CN)6}] (III), and [(SnMe2) 4(μ3-O)2(μ2-OH) 2(H2O)2][{SnMe3 2{Re 6Se8(CN)6}] (IV). The structures of I-IV were determined by X-ray diffraction. Compounds I, IV have the chain structures with the CN-SnMe3-NC bridges between the cluster anions [Re 6Q8(CN)6]4-. Compound II contains isolated fragments {SnMe3(H2O)}2{Re 6Se8(CN)6}2-. In the polymer framework of compound III, the cluster anionic complexes [Re6Se 8(CN)6]4- are bound by the complex cations [(SnMe2)4(μ3-O)2]4+ formed due to the hydrolysis of the initial (SnMe3)Cl.

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U2 - 10.1134/S1070328407120020

DO - 10.1134/S1070328407120020

M3 - Article

AN - SCOPUS:37549001723

SN - 1070-3284

VL - 33

SP - 876

EP - 885

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

IS - 12

ER -

Synthesis and structure of novel coordination compounds based on [Re 6Q8(CN)6]4- (Q = S, Se) and (SnMe3)+

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Synthesis and structure of novel coordination compounds based on [Re ₆Q₈(CN)₆]^4- (Q = S, Se) and (SnMe₃)⁺