Synthesis and reactivity of rhenium cluster-supported manganese porphyrin complexes

Youngmee Kim; Sun Kyung Choi; Seon Mi Park; Wonwoo Nam; Sung Jin Kim

doi:10.1016/S1387-7003(02)00505-1

Synthesis and reactivity of rhenium cluster-supported manganese porphyrin complexes

Youngmee Kim, Sun Kyung Choi, Seon Mi Park, Wonwoo Nam, Sung Jin Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The first discrete molecules of rhenium cluster-supported Mn(OEP) and Mn(TPP) complexes have been synthesized. The Mn(TPP)-containing rhenium cluster as a heterogeneous catalyst showed a high catalytic activity in the epoxidation of olefins by iodosylbenzene.

Original language	English
Pages (from-to)	612-615
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	5
Issue number	8
DOIs	https://doi.org/10.1016/S1387-7003(02)00505-1
State	Published - 2002

Bibliographical note

Funding Information:
This research was supported by the Korea Science & Engineering Foundation (R01-2000-000-00045-0 to S.-J.K., R03-2000-000-00002-0 to Y.K., and R02-2001-000-00028-0 to W.N.). We thank Dr. Alan J. Lough at the University of Toronto in Canada for the X-ray data collection.

Keywords

Cluster compounds
Cyanide complexes
Heterogeneous catalyst
Manganese(III) porphyrines
Rhenium complexes

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10.1016/S1387-7003(02)00505-1

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title = "Synthesis and reactivity of rhenium cluster-supported manganese porphyrin complexes",

abstract = "The first discrete molecules of rhenium cluster-supported Mn(OEP) and Mn(TPP) complexes have been synthesized. The Mn(TPP)-containing rhenium cluster as a heterogeneous catalyst showed a high catalytic activity in the epoxidation of olefins by iodosylbenzene.",

keywords = "Cluster compounds, Cyanide complexes, Heterogeneous catalyst, Manganese(III) porphyrines, Rhenium complexes",

author = "Youngmee Kim and Choi, \{Sun Kyung\} and Park, \{Seon Mi\} and Wonwoo Nam and Kim, \{Sung Jin\}",

note = "Funding Information: This research was supported by the Korea Science \& Engineering Foundation (R01-2000-000-00045-0 to S.-J.K., R03-2000-000-00002-0 to Y.K., and R02-2001-000-00028-0 to W.N.). We thank Dr. Alan J. Lough at the University of Toronto in Canada for the X-ray data collection.",

year = "2002",

doi = "10.1016/S1387-7003(02)00505-1",

language = "English",

volume = "5",

pages = "612--615",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "8",

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TY - JOUR

T1 - Synthesis and reactivity of rhenium cluster-supported manganese porphyrin complexes

AU - Kim, Youngmee

AU - Choi, Sun Kyung

AU - Park, Seon Mi

AU - Nam, Wonwoo

AU - Kim, Sung Jin

N1 - Funding Information: This research was supported by the Korea Science & Engineering Foundation (R01-2000-000-00045-0 to S.-J.K., R03-2000-000-00002-0 to Y.K., and R02-2001-000-00028-0 to W.N.). We thank Dr. Alan J. Lough at the University of Toronto in Canada for the X-ray data collection.

PY - 2002

Y1 - 2002

N2 - The first discrete molecules of rhenium cluster-supported Mn(OEP) and Mn(TPP) complexes have been synthesized. The Mn(TPP)-containing rhenium cluster as a heterogeneous catalyst showed a high catalytic activity in the epoxidation of olefins by iodosylbenzene.

AB - The first discrete molecules of rhenium cluster-supported Mn(OEP) and Mn(TPP) complexes have been synthesized. The Mn(TPP)-containing rhenium cluster as a heterogeneous catalyst showed a high catalytic activity in the epoxidation of olefins by iodosylbenzene.

KW - Cluster compounds

KW - Cyanide complexes

KW - Heterogeneous catalyst

KW - Manganese(III) porphyrines

KW - Rhenium complexes

UR - https://www.scopus.com/pages/publications/0036329348

U2 - 10.1016/S1387-7003(02)00505-1

DO - 10.1016/S1387-7003(02)00505-1

M3 - Article

AN - SCOPUS:0036329348

SN - 1387-7003

VL - 5

SP - 612

EP - 615

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 8

ER -

Synthesis and reactivity of rhenium cluster-supported manganese porphyrin complexes

Abstract

Bibliographical note

Keywords

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