Synthesis and reactivity of rhenium cluster-supported manganese porphyrin complexes

Youngmee Kim, Sun Kyung Choi, Seon Mi Park, Wonwoo Nam, Sung Jin Kim

Research output: Contribution to journalArticlepeer-review

46 Scopus citations

Abstract

The first discrete molecules of rhenium cluster-supported Mn(OEP) and Mn(TPP) complexes have been synthesized. The Mn(TPP)-containing rhenium cluster as a heterogeneous catalyst showed a high catalytic activity in the epoxidation of olefins by iodosylbenzene.

Original languageEnglish
Pages (from-to)612-615
Number of pages4
JournalInorganic Chemistry Communications
Volume5
Issue number8
DOIs
StatePublished - 2002

Keywords

  • Cluster compounds
  • Cyanide complexes
  • Heterogeneous catalyst
  • Manganese(III) porphyrines
  • Rhenium complexes

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