Synthesis and properties of the conjugated polymers with indenoindene and benzimidazole units for organic photovoltaics

Joo Young Shim, Byoung Hoon Lee, Suhee Song, Heejoo Kim, Ju Ae Kim, Il Kim, Kwanghee Lee, Hongsuk Suh

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

A new electron deficient unit, dimethyl-2H-benzimidazole (MBI), and dihydroindeno[2,1-a]indene (ININE) moiety as electron-rich unit were coupled to synthesize the conjugated polymers containing electron donor-acceptor pair for organic photovoltaics. ININE, MBI, and thiophene (or bithiophene) units were incorporated using Stille and Suzuki polymerization to generate poly(2,7-(5,5,10,10-tetrakis(2-ethylhexyl)-5,10-dihydro- indeno[2,1-a]indene)- alt-5,5-(4′,7′-di-2-thienyl-2,2-dimethyl-2H-benzimidazole)) (PININEDTMBIs) (or PININEBBTMBIs). In MBI, the sulfur at 2-position of 2,1,3-benzothiadiazole (BT) unit was replaced with dialkyl-substituted carbon, whereas keeping the 1,2-quinoid form, to improve the solubility of the polymers. The field-effect hole mobility of PININEBBTMBI was 3.2 × 10-4 cm2/Vs which was improved as compared to that of PININEDTMBI (2.7 × 10-5 cm2/Vs) caused by the introduction of bithiophene units. In case of the most efficient polymer, PININEBBTMBI, the device with the configuration of indium tin oxide (ITO)/poly(3,4- ethylenedioxythiophene) (PEDOT):polystyrene sulfonate (PSS)/polymer:PC 71BM(1:4 w/w)/Al, annealed at 100 C for 10 min demonstrated a open circuit voltage of 0.78 V, a short-circuit current density of 6.66 mA/cm 2, and a fill factor of 0.41, leading to the power conversion efficiency of 2.11%, under white-light illumination (AM 1.5 G, 100 mW/cm 2).

Original languageEnglish
Pages (from-to)241-249
Number of pages9
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume51
Issue number2
DOIs
StatePublished - 15 Jan 2013

Keywords

  • 2H-benzimidazole
  • conjugated polymer
  • copolymerization
  • dihydroindeno[2,1-a]indene
  • synthesis

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