@article{16649d7f9015415689f7570a497a79c9,
title = "Synthesis and crystal structure of a new water-soluble sulfur-containing palladacyclic diaqua complex",
abstract = "A new water-soluble sulfur-containing palladacyclic diaqua complex [(SC)PdII(H2O)2]2 (SO4) {[1]2(SO4), SC = C6H4-2-(CH2StBu)} was synthesized from a reaction of Ag2SO4 with a water-insoluble palladacyclic dichloro complex [(SC)PdII(μ-Cl)]2 (2) in water. Water-solubility of [1]2(SO4) at pH 7 at 25 °C is 9.4 mg/mL. NH4PF6 was added to the solution of [1]2(SO4) in water to give [1](PF6). The structures of [1](PF6) and 2 were unequivocally determined by X-ray analysis.",
keywords = "Aqua complex, Palladacycle, Sulfur",
author = "Keiji Uehara and Shunichi Fukuzumi and Seiji Ogo",
note = "Funding Information: This work was supported by a Grant in aids (15036242, 15350033, 16655022, 17350027, 17655027, 18033041, and 18065017) from the Ministry of Education, Culture, Sports, Science and Technology, Japan, Osaka University 21st Century COE Program, and a CREST program (Nano-Structured Catalysts and Materials) by JST. We thank emeritus Professor M. Misono (University of Tokyo) for valuable discussions.",
year = "2007",
month = jan,
day = "1",
doi = "10.1016/j.jorganchem.2006.08.088",
language = "English",
volume = "692",
pages = "499--504",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "1-3",
}