Superior anion-binding properties of a cryptand-like oligopyrrolic macrocycle

Seong Jin Hong; Jaeduk Yoo; Dae Wi Yoon; Juyoung Yoon; Jong Seung Kim; Chang Hee Lee

doi:10.1002/asia.200900518

Superior anion-binding properties of a cryptand-like oligopyrrolic macrocycle

Seong Jin Hong, Jaeduk Yoo, Dae Wi Yoon, Juyoung Yoon, Jong Seung Kim, Chang Hee Lee

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Recognition by strapped system: Cryptand-type calix[4]pyrrole are shown to exhibit a highly enhanced affinity towards anionic guests as compared to other reported calix[4]pyrroles (see figure). The results obtained provide some insights as to how calix[4]pyrrole-based anion receptors may be designed to achieve higher affinity and selectivity.

Original language	English
Pages (from-to)	768-772
Number of pages	5
Journal	Chemistry - An Asian Journal
Volume	5
Issue number	4
DOIs	https://doi.org/10.1002/asia.200900518
State	Published - 1 Apr 2010

Keywords

Anion-binding
Anion-π interaction
Cryptand calix
Enhanced anion affinity
[4] pyrrole

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10.1002/asia.200900518

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abstract = "Recognition by strapped system: Cryptand-type calix[4]pyrrole are shown to exhibit a highly enhanced affinity towards anionic guests as compared to other reported calix[4]pyrroles (see figure). The results obtained provide some insights as to how calix[4]pyrrole-based anion receptors may be designed to achieve higher affinity and selectivity.",

keywords = "Anion-binding, Anion-π interaction, Cryptand calix, Enhanced anion affinity, [4] pyrrole",

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AU - Yoo, Jaeduk

AU - Yoon, Dae Wi

AU - Yoon, Juyoung

AU - Kim, Jong Seung

AU - Lee, Chang Hee

PY - 2010/4/1

Y1 - 2010/4/1

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AB - Recognition by strapped system: Cryptand-type calix[4]pyrrole are shown to exhibit a highly enhanced affinity towards anionic guests as compared to other reported calix[4]pyrroles (see figure). The results obtained provide some insights as to how calix[4]pyrrole-based anion receptors may be designed to achieve higher affinity and selectivity.

KW - Anion-binding

KW - Anion-π interaction

KW - Cryptand calix

KW - Enhanced anion affinity

KW - [4] pyrrole

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JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

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ER -

Superior anion-binding properties of a cryptand-like oligopyrrolic macrocycle

Abstract

Keywords

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