Structure formation at the interface of liquid/liquid bilayer in electric field

Zhiqun Lin, Tobias Kerle, Thomas P. Russell, Erik Schäffer, Ullrich Steiner

Research output: Contribution to journalArticlepeer-review

156 Scopus citations

Abstract

Subjecting a liquid/liquid interface to an electrohydrodynamic pressure enhances fluctuations with a characteristic wavelength leading to an instability and the formation of well-defined columnar structures. An extension of a linear stability analysis for a single fluid interface to the bilayer case produced general arguments applicable to any interface. Countering the electrohydrodynamic pressure is the Laplace pressure, which for films is dictated by the surface energy; whereas for a bilayer, it is given in terms of the interracial energy. Consequently, the characteristic length scale is reduced in the case of bilayers. Results are presented for different polymer bilayers under a wide range of experimental conditions showing quantitative agreement with the generalized theory with no adjustable parameters. Over 4 orders of magnitude in reduced wavelength and field strength can be described by these arguments. These results point to a viable route by which structures can be produced over a wide range of length scales.

Original languageEnglish
Pages (from-to)3971-3976
Number of pages6
JournalMacromolecules
Volume35
Issue number10
DOIs
StatePublished - 7 May 2002

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