Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO3)2 and Cu(H2O) 22+ units bridged alternatively by btp ligands (btp=2,6-bis(N′-1,2,4-triazolyl)pyridine)

Jin Hong Sung; Soo Seo Jin; Young Ryu Ji; Hwan Lee Jung; Cheal Kim; Sung Jin Kim; Youngmee Kim; Alan J. Lough

doi:10.1016/j.molstruc.2005.05.006

Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO₃)₂ and Cu(H₂O) ₂²⁺ units bridged alternatively by btp ligands (btp=2,6-bis(N′-1,2,4-triazolyl)pyridine)

Jin Hong Sung, Soo Seo Jin, Young Ryu Ji, Hwan Lee Jung, Cheal Kim, Sung Jin Kim, Youngmee Kim, Alan J. Lough

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The reaction of Cu(NO₃)₂ containing NH ₄PF₆ with btp ligands produced a new polymeric compound 1 containing Cu(H2O)22+ and Cu(NO₃)₂ units alternatively bridged by btp ligands with H-bonds between copper-bonded water and nitrate oxygen atoms. Crystal Data: M=1465.97, space group P2/n, a=11.6300(3) Å, b=12.8000(4) Å, c=19.2960(6) Å, β=98.6200(19)°, V=2840.03(15) Å³, Z=2, μ=0.926 mm^-1, Dc=1.714 Mg/m³, R=0.0629, wR=0.1614. The polymeric compound 1 has shown the heterogeneous catalytic activity for the ring opening of epoxides under mild conditions. This catalyst system appears to be an efficient, mild, and easily recyclable method for the alcoholysis of epoxides. In addition, the heterogeneous catalyst 1 has, surprisingly, shown even better catalytic activity than copper salt system in homogeneous condition.

Original language	English
Pages (from-to)	22-28
Number of pages	7
Journal	Journal of Molecular Structure
Volume	751
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2005.05.006
State	Published - 15 Sep 2005

Bibliographical note

Funding Information:
Financial support from the Korean Science and Engineering Foundation (ABRL R14-2003-014-01-001-0 and R01-2005-000-10490-0(2005)) and the Korea Research Foundation (2002-070-C00053) is gratefully acknowledged.

Keywords

Catalyst
Copper complex
Crystal structure
Polymeric compound
Ring opening of epoxide

Access to Document

10.1016/j.molstruc.2005.05.006

Cite this

Sung, J. H., Jin, S. S., Ji, Y. R., Jung, H. L., Kim, C., Kim, S. J., Kim, Y., & Lough, A. J. (2005). Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO₃)₂ and Cu(H₂O) ₂²⁺ units bridged alternatively by btp ligands (btp=2,6-bis(N′-1,2,4-triazolyl)pyridine). Journal of Molecular Structure, 751(1-3), 22-28. https://doi.org/10.1016/j.molstruc.2005.05.006

@article{f0e79c62f94e4205a679ab9519797e4b,

title = "Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO3)2 and Cu(H2O) 22+ units bridged alternatively by btp ligands (btp=2,6-bis(N′-1,2,4-triazolyl)pyridine)",

abstract = "The reaction of Cu(NO3)2 containing NH 4PF6 with btp ligands produced a new polymeric compound 1 containing Cu(H2O)22+ and Cu(NO3)2 units alternatively bridged by btp ligands with H-bonds between copper-bonded water and nitrate oxygen atoms. Crystal Data: M=1465.97, space group P2/n, a=11.6300(3) {\AA}, b=12.8000(4) {\AA}, c=19.2960(6) {\AA}, β=98.6200(19)°, V=2840.03(15) {\AA}3, Z=2, μ=0.926 mm-1, Dc=1.714 Mg/m3, R=0.0629, wR=0.1614. The polymeric compound 1 has shown the heterogeneous catalytic activity for the ring opening of epoxides under mild conditions. This catalyst system appears to be an efficient, mild, and easily recyclable method for the alcoholysis of epoxides. In addition, the heterogeneous catalyst 1 has, surprisingly, shown even better catalytic activity than copper salt system in homogeneous condition.",

keywords = "Catalyst, Copper complex, Crystal structure, Polymeric compound, Ring opening of epoxide",

author = "Sung, {Jin Hong} and Jin, {Soo Seo} and Ji, {Young Ryu} and Jung, {Hwan Lee} and Cheal Kim and Kim, {Sung Jin} and Youngmee Kim and Lough, {Alan J.}",

note = "Funding Information: Financial support from the Korean Science and Engineering Foundation (ABRL R14-2003-014-01-001-0 and R01-2005-000-10490-0(2005)) and the Korea Research Foundation (2002-070-C00053) is gratefully acknowledged.",

year = "2005",

month = sep,

day = "15",

doi = "10.1016/j.molstruc.2005.05.006",

language = "English",

volume = "751",

pages = "22--28",

journal = "Journal of Molecular Structure",

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Sung, JH, Jin, SS, Ji, YR, Jung, HL, Kim, C, Kim, SJ, Kim, Y & Lough, AJ 2005, 'Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO₃)₂ and Cu(H₂O) ₂²⁺ units bridged alternatively by btp ligands (btp=2,6-bis(N′-1,2,4-triazolyl)pyridine)', Journal of Molecular Structure, vol. 751, no. 1-3, pp. 22-28. https://doi.org/10.1016/j.molstruc.2005.05.006

Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO₃)₂ and Cu(H₂O) ₂²⁺ units bridged alternatively by btp ligands (btp=2,6-bis(N′-1,2,4-triazolyl)pyridine). / Sung, Jin Hong; Jin, Soo Seo; Ji, Young Ryu et al.
In: Journal of Molecular Structure, Vol. 751, No. 1-3, 15.09.2005, p. 22-28.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO3)2 and Cu(H2O) 22+ units bridged alternatively by btp ligands (btp=2,6-bis(N′-1,2,4-triazolyl)pyridine)

AU - Sung, Jin Hong

AU - Jin, Soo Seo

AU - Ji, Young Ryu

AU - Jung, Hwan Lee

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

AU - Lough, Alan J.

N1 - Funding Information: Financial support from the Korean Science and Engineering Foundation (ABRL R14-2003-014-01-001-0 and R01-2005-000-10490-0(2005)) and the Korea Research Foundation (2002-070-C00053) is gratefully acknowledged.

PY - 2005/9/15

Y1 - 2005/9/15

N2 - The reaction of Cu(NO3)2 containing NH 4PF6 with btp ligands produced a new polymeric compound 1 containing Cu(H2O)22+ and Cu(NO3)2 units alternatively bridged by btp ligands with H-bonds between copper-bonded water and nitrate oxygen atoms. Crystal Data: M=1465.97, space group P2/n, a=11.6300(3) Å, b=12.8000(4) Å, c=19.2960(6) Å, β=98.6200(19)°, V=2840.03(15) Å3, Z=2, μ=0.926 mm-1, Dc=1.714 Mg/m3, R=0.0629, wR=0.1614. The polymeric compound 1 has shown the heterogeneous catalytic activity for the ring opening of epoxides under mild conditions. This catalyst system appears to be an efficient, mild, and easily recyclable method for the alcoholysis of epoxides. In addition, the heterogeneous catalyst 1 has, surprisingly, shown even better catalytic activity than copper salt system in homogeneous condition.

AB - The reaction of Cu(NO3)2 containing NH 4PF6 with btp ligands produced a new polymeric compound 1 containing Cu(H2O)22+ and Cu(NO3)2 units alternatively bridged by btp ligands with H-bonds between copper-bonded water and nitrate oxygen atoms. Crystal Data: M=1465.97, space group P2/n, a=11.6300(3) Å, b=12.8000(4) Å, c=19.2960(6) Å, β=98.6200(19)°, V=2840.03(15) Å3, Z=2, μ=0.926 mm-1, Dc=1.714 Mg/m3, R=0.0629, wR=0.1614. The polymeric compound 1 has shown the heterogeneous catalytic activity for the ring opening of epoxides under mild conditions. This catalyst system appears to be an efficient, mild, and easily recyclable method for the alcoholysis of epoxides. In addition, the heterogeneous catalyst 1 has, surprisingly, shown even better catalytic activity than copper salt system in homogeneous condition.

KW - Catalyst

KW - Copper complex

KW - Crystal structure

KW - Polymeric compound

KW - Ring opening of epoxide

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DO - 10.1016/j.molstruc.2005.05.006

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