Stoichiometric and electrocatalytic production of hydrogen peroxide driven by a water-soluble copper(ii) complex

Hana Oh; Suhyuk Choi; Joo Yeon Kim; Hyun S. Ahn; Seungwoo Hong

doi:10.1039/c9cc06956a

Stoichiometric and electrocatalytic production of hydrogen peroxide driven by a water-soluble copper(ii) complex

Hana Oh, Suhyuk Choi, Joo Yeon Kim, Hyun S. Ahn, Seungwoo Hong

Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Herein, a water-soluble molecular copper complex was investigated as a catalyst for O₂ reduction in both water and an organic solvent. Although the quasi-stoichiometric oxygen reduction reaction (ORR) for the formation of H₂O₂ was conducted in an organic solvent and revealed mechanistic insights into the ORR, the electrocatalytic production of H₂O₂ was achieved in an aqueous medium.

Original language	English
Pages (from-to)	12659-12662
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	84
DOIs	https://doi.org/10.1039/c9cc06956a
State	Published - 2019

Bibliographical note

Funding Information:
This work was supported by NRF of Korea through MSIP (NRF-2017R1C1B2002037 to S. H. and NRF-2017R1C1B2011074 to H. S. A.) and Sookmyung Women’s University Research Grants (1-1703-2039).

Publisher Copyright:
This journal is © The Royal Society of Chemistry.

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title = "Stoichiometric and electrocatalytic production of hydrogen peroxide driven by a water-soluble copper(ii) complex",

abstract = "Herein, a water-soluble molecular copper complex was investigated as a catalyst for O2 reduction in both water and an organic solvent. Although the quasi-stoichiometric oxygen reduction reaction (ORR) for the formation of H2O2 was conducted in an organic solvent and revealed mechanistic insights into the ORR, the electrocatalytic production of H2O2 was achieved in an aqueous medium.",

author = "Hana Oh and Suhyuk Choi and Kim, {Joo Yeon} and Ahn, {Hyun S.} and Seungwoo Hong",

note = "Funding Information: This work was supported by NRF of Korea through MSIP (NRF-2017R1C1B2002037 to S. H. and NRF-2017R1C1B2011074 to H. S. A.) and Sookmyung Women{\textquoteright}s University Research Grants (1-1703-2039). Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

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doi = "10.1039/c9cc06956a",

language = "English",

volume = "55",

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publisher = "Royal Society of Chemistry",

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T1 - Stoichiometric and electrocatalytic production of hydrogen peroxide driven by a water-soluble copper(ii) complex

AU - Oh, Hana

AU - Choi, Suhyuk

AU - Kim, Joo Yeon

AU - Ahn, Hyun S.

AU - Hong, Seungwoo

N1 - Funding Information: This work was supported by NRF of Korea through MSIP (NRF-2017R1C1B2002037 to S. H. and NRF-2017R1C1B2011074 to H. S. A.) and Sookmyung Women’s University Research Grants (1-1703-2039). Publisher Copyright: This journal is © The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - Herein, a water-soluble molecular copper complex was investigated as a catalyst for O2 reduction in both water and an organic solvent. Although the quasi-stoichiometric oxygen reduction reaction (ORR) for the formation of H2O2 was conducted in an organic solvent and revealed mechanistic insights into the ORR, the electrocatalytic production of H2O2 was achieved in an aqueous medium.

AB - Herein, a water-soluble molecular copper complex was investigated as a catalyst for O2 reduction in both water and an organic solvent. Although the quasi-stoichiometric oxygen reduction reaction (ORR) for the formation of H2O2 was conducted in an organic solvent and revealed mechanistic insights into the ORR, the electrocatalytic production of H2O2 was achieved in an aqueous medium.

UR - http://www.scopus.com/inward/record.url?scp=85073489279&partnerID=8YFLogxK

U2 - 10.1039/c9cc06956a

DO - 10.1039/c9cc06956a

M3 - Article

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AN - SCOPUS:85073489279

SN - 1359-7345

VL - 55

SP - 12659

EP - 12662

JO - Chemical Communications

JF - Chemical Communications

IS - 84

ER -

Stoichiometric and electrocatalytic production of hydrogen peroxide driven by a water-soluble copper(ii) complex

Abstract

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