Stereoselective construction of C-13 quaternary carbon unit of isopimarane diterpene and its synthetic application to isopimarol diterpene

Young Ger Suh, Ra Ok Jun, Jae Kyung Jung, Jae Sang Ryu

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Highly stereoselective construction of the C-13 quaternary carbon unit of isopimarane diterpene has been achieved by two consecutive alkylations of the tricyclic enone intermediate which was straightforwardly derived from the known decalone system. In addition, this procedure has been expanded to the general synthetic route to isopimarane diterpenes.

Original languageEnglish
Pages (from-to)587-593
Number of pages7
JournalSynthetic Communications
Volume27
Issue number4
DOIs
StatePublished - 1997

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