Stereoselective construction of C-13 quaternary carbon unit of isopimarane diterpene and its synthetic application to isopimarol diterpene

Young Ger Suh; Ra Ok Jun; Jae Kyung Jung; Jae Sang Ryu

doi:10.1080/00397919708003329

Stereoselective construction of C-13 quaternary carbon unit of isopimarane diterpene and its synthetic application to isopimarol diterpene

Young Ger Suh, Ra Ok Jun, Jae Kyung Jung, Jae Sang Ryu

Department of Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Highly stereoselective construction of the C-13 quaternary carbon unit of isopimarane diterpene has been achieved by two consecutive alkylations of the tricyclic enone intermediate which was straightforwardly derived from the known decalone system. In addition, this procedure has been expanded to the general synthetic route to isopimarane diterpenes.

Original language	English
Pages (from-to)	587-593
Number of pages	7
Journal	Synthetic Communications
Volume	27
Issue number	4
DOIs	https://doi.org/10.1080/00397919708003329
State	Published - 1997

Bibliographical note

Funding Information:
of Seoul National University for support of this work.

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10.1080/00397919708003329

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title = "Stereoselective construction of C-13 quaternary carbon unit of isopimarane diterpene and its synthetic application to isopimarol diterpene",

abstract = "Highly stereoselective construction of the C-13 quaternary carbon unit of isopimarane diterpene has been achieved by two consecutive alkylations of the tricyclic enone intermediate which was straightforwardly derived from the known decalone system. In addition, this procedure has been expanded to the general synthetic route to isopimarane diterpenes.",

author = "Suh, {Young Ger} and Jun, {Ra Ok} and Jung, {Jae Kyung} and Ryu, {Jae Sang}",

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AU - Suh, Young Ger

AU - Jun, Ra Ok

AU - Jung, Jae Kyung

AU - Ryu, Jae Sang

N1 - Funding Information: of Seoul National University for support of this work.

PY - 1997

Y1 - 1997

N2 - Highly stereoselective construction of the C-13 quaternary carbon unit of isopimarane diterpene has been achieved by two consecutive alkylations of the tricyclic enone intermediate which was straightforwardly derived from the known decalone system. In addition, this procedure has been expanded to the general synthetic route to isopimarane diterpenes.

AB - Highly stereoselective construction of the C-13 quaternary carbon unit of isopimarane diterpene has been achieved by two consecutive alkylations of the tricyclic enone intermediate which was straightforwardly derived from the known decalone system. In addition, this procedure has been expanded to the general synthetic route to isopimarane diterpenes.

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DO - 10.1080/00397919708003329

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VL - 27

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EP - 593

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ER -

Stereoselective construction of C-13 quaternary carbon unit of isopimarane diterpene and its synthetic application to isopimarol diterpene

Abstract

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