Stability of carbon clusters CN for 46 ≤ N ≤ 102

P. E. Barran; S. Firth; A. J. Stace; H. W. Kroto; K. Hansen; E. E.B. Campbell

doi:10.1016/s0168-1176(97)00038-4

Stability of carbon clusters C_N for 46 ≤ N ≤ 102

P. E. Barran, S. Firth, A. J. Stace, H. W. Kroto, K. Hansen, E. E.B. Campbell

Department of Physics

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Relative binding energies for C⁺_N-2-C₂ have been determined for fullerene ions in the range 46 ≤ N ≤ 102. The values were derived from metastable fractions observed in a time-of-flight reflectron mass spectrometer. The timescale of the experiments was such that radiative cooling of the fullerene ions did not play an important role thus simplifying the data analysis. The results are compared with previous values of relative dissociation energies for C₂ loss given in the literature. It was found that the relative C₂ dissociation energies for large fullerenes (N > 60) are significantly higher than previously estimated.

Original language	English
Pages (from-to)	127-133
Number of pages	7
Journal	International Journal of Mass Spectrometry and Ion Processes
Volume	167-168
DOIs	https://doi.org/10.1016/s0168-1176(97)00038-4
State	Published - 1997

Bibliographical note

Funding Information:
Financial support from the EU through HCM Network "Formation, Stability and Photophysics of Fullerenes", the ERSRC and the Royal Society is gratefully acknowledged.

Keywords

Dissociation energies
Fullerenes
Metastable fragmentation

Access to Document

10.1016/s0168-1176(97)00038-4

Cite this

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title = "Stability of carbon clusters CN for 46 ≤ N ≤ 102",

abstract = "Relative binding energies for C+N-2-C2 have been determined for fullerene ions in the range 46 ≤ N ≤ 102. The values were derived from metastable fractions observed in a time-of-flight reflectron mass spectrometer. The timescale of the experiments was such that radiative cooling of the fullerene ions did not play an important role thus simplifying the data analysis. The results are compared with previous values of relative dissociation energies for C2 loss given in the literature. It was found that the relative C2 dissociation energies for large fullerenes (N > 60) are significantly higher than previously estimated.",

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author = "Barran, {P. E.} and S. Firth and Stace, {A. J.} and Kroto, {H. W.} and K. Hansen and Campbell, {E. E.B.}",

note = "Funding Information: Financial support from the EU through HCM Network {"}Formation, Stability and Photophysics of Fullerenes{"}, the ERSRC and the Royal Society is gratefully acknowledged.",

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doi = "10.1016/s0168-1176(97)00038-4",

language = "English",

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pages = "127--133",

journal = "International Journal of Mass Spectrometry and Ion Processes",

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TY - JOUR

T1 - Stability of carbon clusters CN for 46 ≤ N ≤ 102

AU - Barran, P. E.

AU - Firth, S.

AU - Stace, A. J.

AU - Kroto, H. W.

AU - Hansen, K.

AU - Campbell, E. E.B.

N1 - Funding Information: Financial support from the EU through HCM Network "Formation, Stability and Photophysics of Fullerenes", the ERSRC and the Royal Society is gratefully acknowledged.

PY - 1997

Y1 - 1997

N2 - Relative binding energies for C+N-2-C2 have been determined for fullerene ions in the range 46 ≤ N ≤ 102. The values were derived from metastable fractions observed in a time-of-flight reflectron mass spectrometer. The timescale of the experiments was such that radiative cooling of the fullerene ions did not play an important role thus simplifying the data analysis. The results are compared with previous values of relative dissociation energies for C2 loss given in the literature. It was found that the relative C2 dissociation energies for large fullerenes (N > 60) are significantly higher than previously estimated.

AB - Relative binding energies for C+N-2-C2 have been determined for fullerene ions in the range 46 ≤ N ≤ 102. The values were derived from metastable fractions observed in a time-of-flight reflectron mass spectrometer. The timescale of the experiments was such that radiative cooling of the fullerene ions did not play an important role thus simplifying the data analysis. The results are compared with previous values of relative dissociation energies for C2 loss given in the literature. It was found that the relative C2 dissociation energies for large fullerenes (N > 60) are significantly higher than previously estimated.

KW - Dissociation energies

KW - Fullerenes

KW - Metastable fragmentation

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