Sr11Cd6Sb12: A new Zint1 compound with infinite chains of pentagonal tubes

Seon Mi Park; Sung Jin Kim

doi:10.1016/j.jssc.2004.05.037

Sr₁₁Cd₆Sb₁₂: A new Zint1 compound with infinite chains of pentagonal tubes

Seon Mi Park, Sung Jin Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

A new Cd-containing transition metal Zintl phase, Sr₁₁Cd ₆Sb₁₂, was obtained from a direct element combination reaction using the Sn flux method. Its structure was determined using single-crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/m with a=32.903(3)Å, b=4.7666(5)Å, c=12.6057(13)Å, β=109.752(2)°, and Z=2. Sr₁₁Cd ₆Sb₁₂ has a one-dimensional infinite chain structure consisting of double pentagonal tubes, where Sr²⁺ cations reside both within two tubes and between the infinite chains of tubes. The anionic framework [Cd₆Sb₁₂]^22- has features similar to those of Eu₁₀Mn₆Sb₁₃. The difference in Eu ₁₀Mn₆Sb₁₃ is that its double pentagonal tubes are further condensed to form two-dimensional layers.

Original language	English
Pages (from-to)	3418-3422
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	177
Issue number	10
DOIs	https://doi.org/10.1016/j.jssc.2004.05.037
State	Published - Oct 2004

Bibliographical note

Funding Information:
This work was supported by the Korean Science and Engineering Foundation (ABRL R14-2003-014-01000-0). We thank Prof. Moon Gun Choi in Yonsei University for the X-ray data collection.

Keywords

CdSb tetrahedra
Double pentagonal tubes
Ternary antimonide
Zintl phase

Access to Document

10.1016/j.jssc.2004.05.037

Cite this

@article{838c282eb69540e282c0d023f7885496,

title = "Sr11Cd6Sb12: A new Zint1 compound with infinite chains of pentagonal tubes",

abstract = "A new Cd-containing transition metal Zintl phase, Sr11Cd 6Sb12, was obtained from a direct element combination reaction using the Sn flux method. Its structure was determined using single-crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/m with a=32.903(3){\AA}, b=4.7666(5){\AA}, c=12.6057(13){\AA}, β=109.752(2)°, and Z=2. Sr11Cd 6Sb12 has a one-dimensional infinite chain structure consisting of double pentagonal tubes, where Sr2+ cations reside both within two tubes and between the infinite chains of tubes. The anionic framework [Cd6Sb12]22- has features similar to those of Eu10Mn6Sb13. The difference in Eu 10Mn6Sb13 is that its double pentagonal tubes are further condensed to form two-dimensional layers.",

keywords = "CdSb tetrahedra, Double pentagonal tubes, Ternary antimonide, Zintl phase",

author = "Park, {Seon Mi} and Kim, {Sung Jin}",

note = "Funding Information: This work was supported by the Korean Science and Engineering Foundation (ABRL R14-2003-014-01000-0). We thank Prof. Moon Gun Choi in Yonsei University for the X-ray data collection.",

year = "2004",

month = oct,

doi = "10.1016/j.jssc.2004.05.037",

language = "English",

volume = "177",

pages = "3418--3422",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Sr11Cd6Sb12

T2 - A new Zint1 compound with infinite chains of pentagonal tubes

AU - Park, Seon Mi

AU - Kim, Sung Jin

N1 - Funding Information: This work was supported by the Korean Science and Engineering Foundation (ABRL R14-2003-014-01000-0). We thank Prof. Moon Gun Choi in Yonsei University for the X-ray data collection.

PY - 2004/10

Y1 - 2004/10

N2 - A new Cd-containing transition metal Zintl phase, Sr11Cd 6Sb12, was obtained from a direct element combination reaction using the Sn flux method. Its structure was determined using single-crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/m with a=32.903(3)Å, b=4.7666(5)Å, c=12.6057(13)Å, β=109.752(2)°, and Z=2. Sr11Cd 6Sb12 has a one-dimensional infinite chain structure consisting of double pentagonal tubes, where Sr2+ cations reside both within two tubes and between the infinite chains of tubes. The anionic framework [Cd6Sb12]22- has features similar to those of Eu10Mn6Sb13. The difference in Eu 10Mn6Sb13 is that its double pentagonal tubes are further condensed to form two-dimensional layers.

AB - A new Cd-containing transition metal Zintl phase, Sr11Cd 6Sb12, was obtained from a direct element combination reaction using the Sn flux method. Its structure was determined using single-crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/m with a=32.903(3)Å, b=4.7666(5)Å, c=12.6057(13)Å, β=109.752(2)°, and Z=2. Sr11Cd 6Sb12 has a one-dimensional infinite chain structure consisting of double pentagonal tubes, where Sr2+ cations reside both within two tubes and between the infinite chains of tubes. The anionic framework [Cd6Sb12]22- has features similar to those of Eu10Mn6Sb13. The difference in Eu 10Mn6Sb13 is that its double pentagonal tubes are further condensed to form two-dimensional layers.

KW - CdSb tetrahedra

KW - Double pentagonal tubes

KW - Ternary antimonide

KW - Zintl phase

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U2 - 10.1016/j.jssc.2004.05.037

DO - 10.1016/j.jssc.2004.05.037

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