Spin-site exchange system constructed from endohedral metallofullerenes and organic donors

Takahiro Tsuchiya; Kumiko Sato; Hiroki Kurihara; Takatsugu Wakahara; Yutaka Maeda; Takeshi Akasaka; Kei Ohkubo; Shunichi Fukuzumi; Tatsuhisa Kato; Shigeru Nagase

doi:10.1021/ja062634x

Spin-site exchange system constructed from endohedral metallofullerenes and organic donors

Takahiro Tsuchiya
, Kumiko Sato
, Hiroki Kurihara
, Takatsugu Wakahara
, Yutaka Maeda
, Takeshi Akasaka
, Kei Ohkubo
, Shunichi Fukuzumi
, Tatsuhisa Kato
, Shigeru Nagase

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Complexation behavior of the paramagnetic La@C₈₂ metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C₈₂ and D form a 1:1 complex as a result of electron transfer. La@C₈₂ and D are in equilibrium with [La@C₈₂]^-/[D]^•+ in solution, which is readily controllable by changing the temperature and solvent.

Original language	English
Pages (from-to)	14418-14419
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	45
DOIs	https://doi.org/10.1021/ja062634x
State	Published - 15 Nov 2006

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title = "Spin-site exchange system constructed from endohedral metallofullerenes and organic donors",

abstract = "Complexation behavior of the paramagnetic La@C82 metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C82 and D form a 1:1 complex as a result of electron transfer. La@C82 and D are in equilibrium with [La@C82]-/[D]•+ in solution, which is readily controllable by changing the temperature and solvent.",

author = "Takahiro Tsuchiya and Kumiko Sato and Hiroki Kurihara and Takatsugu Wakahara and Yutaka Maeda and Takeshi Akasaka and Kei Ohkubo and Shunichi Fukuzumi and Tatsuhisa Kato and Shigeru Nagase",

year = "2006",

month = nov,

day = "15",

doi = "10.1021/ja062634x",

language = "English",

volume = "128",

pages = "14418--14419",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Spin-site exchange system constructed from endohedral metallofullerenes and organic donors

AU - Tsuchiya, Takahiro

AU - Sato, Kumiko

AU - Kurihara, Hiroki

AU - Wakahara, Takatsugu

AU - Maeda, Yutaka

AU - Akasaka, Takeshi

AU - Ohkubo, Kei

AU - Fukuzumi, Shunichi

AU - Kato, Tatsuhisa

AU - Nagase, Shigeru

PY - 2006/11/15

Y1 - 2006/11/15

N2 - Complexation behavior of the paramagnetic La@C82 metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C82 and D form a 1:1 complex as a result of electron transfer. La@C82 and D are in equilibrium with [La@C82]-/[D]•+ in solution, which is readily controllable by changing the temperature and solvent.

AB - Complexation behavior of the paramagnetic La@C82 metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C82 and D form a 1:1 complex as a result of electron transfer. La@C82 and D are in equilibrium with [La@C82]-/[D]•+ in solution, which is readily controllable by changing the temperature and solvent.

UR - https://www.scopus.com/pages/publications/33751016803

U2 - 10.1021/ja062634x

DO - 10.1021/ja062634x

M3 - Article

AN - SCOPUS:33751016803

SN - 0002-7863

VL - 128

SP - 14418

EP - 14419

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 45

ER -

Spin-site exchange system constructed from endohedral metallofullerenes and organic donors

Abstract

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