Spin-site exchange system constructed from endohedral metallofullerenes and organic donors

Takahiro Tsuchiya; Kumiko Sato; Hiroki Kurihara; Takatsugu Wakahara; Yutaka Maeda; Takeshi Akasaka; Kei Ohkubo; Shunichi Fukuzumi; Tatsuhisa Kato; Shigeru Nagase

doi:10.1021/ja062634x

Spin-site exchange system constructed from endohedral metallofullerenes and organic donors

Takahiro Tsuchiya, Kumiko Sato, Hiroki Kurihara, Takatsugu Wakahara, Yutaka Maeda, Takeshi Akasaka, Kei Ohkubo, Shunichi Fukuzumi, Tatsuhisa Kato, Shigeru Nagase

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Complexation behavior of the paramagnetic La@C₈₂ metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C₈₂ and D form a 1:1 complex as a result of electron transfer. La@C₈₂ and D are in equilibrium with [La@C₈₂]^-/[D]^•+ in solution, which is readily controllable by changing the temperature and solvent.

Original language	English
Pages (from-to)	14418-14419
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	45
DOIs	https://doi.org/10.1021/ja062634x
State	Published - 15 Nov 2006

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title = "Spin-site exchange system constructed from endohedral metallofullerenes and organic donors",

abstract = "Complexation behavior of the paramagnetic La@C82 metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C82 and D form a 1:1 complex as a result of electron transfer. La@C82 and D are in equilibrium with [La@C82]-/[D]•+ in solution, which is readily controllable by changing the temperature and solvent.",

author = "Takahiro Tsuchiya and Kumiko Sato and Hiroki Kurihara and Takatsugu Wakahara and Yutaka Maeda and Takeshi Akasaka and Kei Ohkubo and Shunichi Fukuzumi and Tatsuhisa Kato and Shigeru Nagase",

year = "2006",

month = nov,

day = "15",

doi = "10.1021/ja062634x",

language = "English",

volume = "128",

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journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Spin-site exchange system constructed from endohedral metallofullerenes and organic donors

AU - Tsuchiya, Takahiro

AU - Sato, Kumiko

AU - Kurihara, Hiroki

AU - Wakahara, Takatsugu

AU - Maeda, Yutaka

AU - Akasaka, Takeshi

AU - Ohkubo, Kei

AU - Fukuzumi, Shunichi

AU - Kato, Tatsuhisa

AU - Nagase, Shigeru

PY - 2006/11/15

Y1 - 2006/11/15

N2 - Complexation behavior of the paramagnetic La@C82 metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C82 and D form a 1:1 complex as a result of electron transfer. La@C82 and D are in equilibrium with [La@C82]-/[D]•+ in solution, which is readily controllable by changing the temperature and solvent.

AB - Complexation behavior of the paramagnetic La@C82 metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C82 and D form a 1:1 complex as a result of electron transfer. La@C82 and D are in equilibrium with [La@C82]-/[D]•+ in solution, which is readily controllable by changing the temperature and solvent.

UR - http://www.scopus.com/inward/record.url?scp=33751016803&partnerID=8YFLogxK

U2 - 10.1021/ja062634x

DO - 10.1021/ja062634x

M3 - Article

AN - SCOPUS:33751016803

SN - 0002-7863

VL - 128

SP - 14418

EP - 14419

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 45

ER -

Spin-site exchange system constructed from endohedral metallofullerenes and organic donors

Abstract

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