Spin-site exchange system constructed from endohedral metallofullerenes and organic donors

Takahiro Tsuchiya, Kumiko Sato, Hiroki Kurihara, Takatsugu Wakahara, Yutaka Maeda, Takeshi Akasaka, Kei Ohkubo, Shunichi Fukuzumi, Tatsuhisa Kato, Shigeru Nagase

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Abstract

Complexation behavior of the paramagnetic La@C82 metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C82 and D form a 1:1 complex as a result of electron transfer. La@C82 and D are in equilibrium with [La@C82]-/[D]•+ in solution, which is readily controllable by changing the temperature and solvent.

Original languageEnglish
Pages (from-to)14418-14419
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number45
DOIs
StatePublished - 15 Nov 2006

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