Specific naked eye sensing of cyanide by chromogenic host: Studies on the effect of solvents

Jongmin Kang; Eun Joo Song; Hyun Kim; Young Hee Kim; Youngmee Kim; Sung Jin Kim; Cheal Kim

doi:10.1016/j.tetlet.2012.12.053

Specific naked eye sensing of cyanide by chromogenic host: Studies on the effect of solvents

Jongmin Kang, Eun Joo Song, Hyun Kim, Young Hee Kim, Youngmee Kim, Sung Jin Kim, Cheal Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

We have synthesized receptor 1, which showed high selectivity toward CN^- over other competitive anions in protic solvents. In addition, it distinguished CN^- from other anions by color changes. Furthermore, its detection limit is far below the WHO guidelines of drinking water. However, in aprotic solvents such as acetonitrile, the unique selectivity for CN ^- disappeared, and the nonselective color change was observed for strongly basic anions such as F^-, AcO^-, and H ₂PO₄^-. These results suggest that receptor 1 interacts with cyanide with different mechanisms depending on solvents. The interaction mechanisms between 1 and cyanide in protic and aprotic solvents were investigated.

Original language	English
Pages (from-to)	1015-1019
Number of pages	5
Journal	Tetrahedron Letters
Volume	54
Issue number	8
DOIs	https://doi.org/10.1016/j.tetlet.2012.12.053
State	Published - 20 Feb 2013

Bibliographical note

Funding Information:
This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2010-0021333 , 2012001725 , 2011K000675 , and 2012008875 ).

Keywords

Chemodosimetric approach
Colorimetric sensing
Cyanide sensing
Naked eye sensing
Solvents effects

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10.1016/j.tetlet.2012.12.053

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title = "Specific naked eye sensing of cyanide by chromogenic host: Studies on the effect of solvents",

abstract = "We have synthesized receptor 1, which showed high selectivity toward CN- over other competitive anions in protic solvents. In addition, it distinguished CN- from other anions by color changes. Furthermore, its detection limit is far below the WHO guidelines of drinking water. However, in aprotic solvents such as acetonitrile, the unique selectivity for CN - disappeared, and the nonselective color change was observed for strongly basic anions such as F-, AcO-, and H 2PO4-. These results suggest that receptor 1 interacts with cyanide with different mechanisms depending on solvents. The interaction mechanisms between 1 and cyanide in protic and aprotic solvents were investigated.",

keywords = "Chemodosimetric approach, Colorimetric sensing, Cyanide sensing, Naked eye sensing, Solvents effects",

author = "Jongmin Kang and Song, {Eun Joo} and Hyun Kim and Kim, {Young Hee} and Youngmee Kim and Kim, {Sung Jin} and Cheal Kim",

note = "Funding Information: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2010-0021333 , 2012001725 , 2011K000675 , and 2012008875 ). ",

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AU - Kang, Jongmin

AU - Song, Eun Joo

AU - Kim, Hyun

AU - Kim, Young Hee

AU - Kim, Youngmee

AU - Kim, Sung Jin

AU - Kim, Cheal

N1 - Funding Information: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2010-0021333 , 2012001725 , 2011K000675 , and 2012008875 ).

PY - 2013/2/20

Y1 - 2013/2/20

N2 - We have synthesized receptor 1, which showed high selectivity toward CN- over other competitive anions in protic solvents. In addition, it distinguished CN- from other anions by color changes. Furthermore, its detection limit is far below the WHO guidelines of drinking water. However, in aprotic solvents such as acetonitrile, the unique selectivity for CN - disappeared, and the nonselective color change was observed for strongly basic anions such as F-, AcO-, and H 2PO4-. These results suggest that receptor 1 interacts with cyanide with different mechanisms depending on solvents. The interaction mechanisms between 1 and cyanide in protic and aprotic solvents were investigated.

AB - We have synthesized receptor 1, which showed high selectivity toward CN- over other competitive anions in protic solvents. In addition, it distinguished CN- from other anions by color changes. Furthermore, its detection limit is far below the WHO guidelines of drinking water. However, in aprotic solvents such as acetonitrile, the unique selectivity for CN - disappeared, and the nonselective color change was observed for strongly basic anions such as F-, AcO-, and H 2PO4-. These results suggest that receptor 1 interacts with cyanide with different mechanisms depending on solvents. The interaction mechanisms between 1 and cyanide in protic and aprotic solvents were investigated.

KW - Chemodosimetric approach

KW - Colorimetric sensing

KW - Cyanide sensing

KW - Naked eye sensing

KW - Solvents effects

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JO - Tetrahedron Letters

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ER -

Specific naked eye sensing of cyanide by chromogenic host: Studies on the effect of solvents

Abstract

Bibliographical note

Keywords

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