Single-Step Synthesis of Mesoporous Carbon Nitride/Molybdenum Sulfide Nanohybrids for High-Performance Sodium-Ion Batteries

Molybdenum disulfide (MoS₂) is a promising candidate as a high-performing anode material for sodium-ion batteries (SIBs) due to its large interlayer spacing. However, it suffers from continued capacity fading. This problem could be overcome by hybridizing MoS₂ with nanostructured carbon-based materials, but it is quite challenging. Herein, we demonstrate a single-step strategy for the preparation of MoS₂ coupled with ordered mesoporous carbon nitride using a nanotemplating approach which involves the pyrolysis of phosphomolybdic acid hydrate (PMA), dithiooxamide (DTO) and 5-amino-1H-tetrazole (5-ATTZ) together in the porous channels of 3D mesoporous silica template. The sulfidation to MoS₂, polymerization to carbon nitride (CN) and their hybridization occur simultaneously within a mesoporous silica template during a calcination process. The CN/MoS₂ hybrid prepared by this unique approach is highly pure and exhibits good crystallinity as well as delivers excellent performance for SIBs with specific capacities of 605 and 431 mAhg⁻¹ at current densities of 100 and 1000 mAg⁻¹, respectively, for SIBs.