Single electron transfer Diels-Alder reaction of fullerene with Danishefsky's diene

Koichi Mikami; Shoji Matsumoto; Yasutaka Okubo; Tomoyoshi Suenobu; Shunichi Fukuzumi

doi:10.1055/s-1999-2776

Single electron transfer Diels-Alder reaction of fullerene with Danishefsky's diene

Koichi Mikami, Shoji Matsumoto, Yasutaka Okubo, Tomoyoshi Suenobu, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Single electron transfer mechanism in the Diels-Alder reactions of fullerene with Danishefsky's diene (1) is described. The Diels-Alder reactions proceed by stepwise mechanism via a single electron transfer from 1 to C₆₀ under not only thermal but also photochemical conditions. The observed rate constant agrees well with the predicted rate constant on the basis of the single electron transfer mechanism.

Original language	English
Pages (from-to)	1130-1132
Number of pages	3
Journal	Synlett
Issue number	7
DOIs	https://doi.org/10.1055/s-1999-2776
State	Published - 1999

Keywords

Danishefsky's diene
Diels-Alder reaction
Fullerene
Single electron transfer

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10.1055/s-1999-2776

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title = "Single electron transfer Diels-Alder reaction of fullerene with Danishefsky's diene",

abstract = "Single electron transfer mechanism in the Diels-Alder reactions of fullerene with Danishefsky's diene (1) is described. The Diels-Alder reactions proceed by stepwise mechanism via a single electron transfer from 1 to C60 under not only thermal but also photochemical conditions. The observed rate constant agrees well with the predicted rate constant on the basis of the single electron transfer mechanism.",

keywords = "Danishefsky's diene, Diels-Alder reaction, Fullerene, Single electron transfer",

author = "Koichi Mikami and Shoji Matsumoto and Yasutaka Okubo and Tomoyoshi Suenobu and Shunichi Fukuzumi",

year = "1999",

doi = "10.1055/s-1999-2776",

language = "English",

pages = "1130--1132",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "7",

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TY - JOUR

T1 - Single electron transfer Diels-Alder reaction of fullerene with Danishefsky's diene

AU - Mikami, Koichi

AU - Matsumoto, Shoji

AU - Okubo, Yasutaka

AU - Suenobu, Tomoyoshi

AU - Fukuzumi, Shunichi

PY - 1999

Y1 - 1999

N2 - Single electron transfer mechanism in the Diels-Alder reactions of fullerene with Danishefsky's diene (1) is described. The Diels-Alder reactions proceed by stepwise mechanism via a single electron transfer from 1 to C60 under not only thermal but also photochemical conditions. The observed rate constant agrees well with the predicted rate constant on the basis of the single electron transfer mechanism.

AB - Single electron transfer mechanism in the Diels-Alder reactions of fullerene with Danishefsky's diene (1) is described. The Diels-Alder reactions proceed by stepwise mechanism via a single electron transfer from 1 to C60 under not only thermal but also photochemical conditions. The observed rate constant agrees well with the predicted rate constant on the basis of the single electron transfer mechanism.

KW - Danishefsky's diene

KW - Diels-Alder reaction

KW - Fullerene

KW - Single electron transfer

UR - http://www.scopus.com/inward/record.url?scp=0032813743&partnerID=8YFLogxK

U2 - 10.1055/s-1999-2776

DO - 10.1055/s-1999-2776

M3 - Article

AN - SCOPUS:0032813743

SN - 0936-5214

SP - 1130

EP - 1132

JO - Synlett

JF - Synlett

IS - 7

ER -

Single electron transfer Diels-Alder reaction of fullerene with Danishefsky's diene

Abstract

Keywords

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