Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2 + 2] photodimerization assisted by a coexisting flexible ligand

Jae Hwa Lee; Sungbin Park; Sungeun Jeoung; Hoi Ri Moon

doi:10.1039/c6ce02652d

Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2 + 2] photodimerization assisted by a coexisting flexible ligand

Jae Hwa Lee, Sungbin Park, Sungeun Jeoung, Hoi Ri Moon

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A 2D interdigitated [Ni₂(adipate)₂(spy)₄(H₂O)₂] (spy = 4-styrylpyridine) was transformed to a 3D coordination polymer through [2 + 2] photodimerization between the olefin bonds in spy upon UV-irradiation in a single-crystal-to-single-crystal (SC-SC) manner. During this transformation, a coexisting flexible adipate ligand changes its conformation, and helps in withstanding the conversion strain and retaining the single crystallinity.

Original language	English
Pages (from-to)	3719-3722
Number of pages	4
Journal	CrystEngComm
Volume	19
Issue number	27
DOIs	https://doi.org/10.1039/c6ce02652d
State	Published - 2017

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© 2017 The Royal Society of Chemistry.

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title = "Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2 + 2] photodimerization assisted by a coexisting flexible ligand",

abstract = "A 2D interdigitated [Ni2(adipate)2(spy)4(H2O)2] (spy = 4-styrylpyridine) was transformed to a 3D coordination polymer through [2 + 2] photodimerization between the olefin bonds in spy upon UV-irradiation in a single-crystal-to-single-crystal (SC-SC) manner. During this transformation, a coexisting flexible adipate ligand changes its conformation, and helps in withstanding the conversion strain and retaining the single crystallinity.",

author = "Lee, {Jae Hwa} and Sungbin Park and Sungeun Jeoung and Moon, {Hoi Ri}",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6ce02652d",

language = "English",

volume = "19",

pages = "3719--3722",

journal = "CrystEngComm",

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publisher = "Royal Society of Chemistry",

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T1 - Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2 + 2] photodimerization assisted by a coexisting flexible ligand

AU - Lee, Jae Hwa

AU - Park, Sungbin

AU - Jeoung, Sungeun

AU - Moon, Hoi Ri

PY - 2017

Y1 - 2017

N2 - A 2D interdigitated [Ni2(adipate)2(spy)4(H2O)2] (spy = 4-styrylpyridine) was transformed to a 3D coordination polymer through [2 + 2] photodimerization between the olefin bonds in spy upon UV-irradiation in a single-crystal-to-single-crystal (SC-SC) manner. During this transformation, a coexisting flexible adipate ligand changes its conformation, and helps in withstanding the conversion strain and retaining the single crystallinity.

AB - A 2D interdigitated [Ni2(adipate)2(spy)4(H2O)2] (spy = 4-styrylpyridine) was transformed to a 3D coordination polymer through [2 + 2] photodimerization between the olefin bonds in spy upon UV-irradiation in a single-crystal-to-single-crystal (SC-SC) manner. During this transformation, a coexisting flexible adipate ligand changes its conformation, and helps in withstanding the conversion strain and retaining the single crystallinity.

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U2 - 10.1039/c6ce02652d

DO - 10.1039/c6ce02652d

M3 - Article

AN - SCOPUS:85023209412

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VL - 19

SP - 3719

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JO - CrystEngComm

JF - CrystEngComm

IS - 27

ER -

Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2 + 2] photodimerization assisted by a coexisting flexible ligand

Abstract

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