Silicon-containing dendritic tris-cyclometalated Ir(iii) complex and its electrophosphorescence in a polymer host

Youngmin You; Cheng Guo An; Deug Sang Lee; Jang Joo Kim; Soo Young Park

doi:10.1039/b611288a

Silicon-containing dendritic tris-cyclometalated Ir(iii) complex and its electrophosphorescence in a polymer host

Youngmin You, Cheng Guo An, Deug Sang Lee, Jang Joo Kim, Soo Young Park

Department of Chemical Engineering & Materials Science

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

In this paper, we present the synthesis and characterization of a new highly phosphorescent cyclometalated Ir(iii) complex with a silane-based dendritic substituent. The Ir(iii) complex showed 74 ± 3% of absolute phosphorescence quantum efficiency in the film state. In addition, efficient electrophosphorescence (32.8 cd A^-1) employing an Ir(iii) complex-poly(N-vinylcarbazole) system device is observed. Study of a series of electroluminescent, spectroscopic, and electrochemical data of the Ir(iii) complex and the reference Ir(ppy)₃ reveals superior performance of the new Ir(iii) complex.

Original language	English
Pages (from-to)	4706-4713
Number of pages	8
Journal	Journal of Materials Chemistry
Volume	16
Issue number	48
DOIs	https://doi.org/10.1039/b611288a
State	Published - 2006

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title = "Silicon-containing dendritic tris-cyclometalated Ir(iii) complex and its electrophosphorescence in a polymer host",

abstract = "In this paper, we present the synthesis and characterization of a new highly phosphorescent cyclometalated Ir(iii) complex with a silane-based dendritic substituent. The Ir(iii) complex showed 74 ± 3\% of absolute phosphorescence quantum efficiency in the film state. In addition, efficient electrophosphorescence (32.8 cd A-1) employing an Ir(iii) complex-poly(N-vinylcarbazole) system device is observed. Study of a series of electroluminescent, spectroscopic, and electrochemical data of the Ir(iii) complex and the reference Ir(ppy)3 reveals superior performance of the new Ir(iii) complex.",

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year = "2006",

doi = "10.1039/b611288a",

language = "English",

volume = "16",

pages = "4706--4713",

journal = "Journal of Materials Chemistry",

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publisher = "Royal Society of Chemistry",

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T1 - Silicon-containing dendritic tris-cyclometalated Ir(iii) complex and its electrophosphorescence in a polymer host

AU - You, Youngmin

AU - An, Cheng Guo

AU - Lee, Deug Sang

AU - Kim, Jang Joo

AU - Park, Soo Young

PY - 2006

Y1 - 2006

N2 - In this paper, we present the synthesis and characterization of a new highly phosphorescent cyclometalated Ir(iii) complex with a silane-based dendritic substituent. The Ir(iii) complex showed 74 ± 3% of absolute phosphorescence quantum efficiency in the film state. In addition, efficient electrophosphorescence (32.8 cd A-1) employing an Ir(iii) complex-poly(N-vinylcarbazole) system device is observed. Study of a series of electroluminescent, spectroscopic, and electrochemical data of the Ir(iii) complex and the reference Ir(ppy)3 reveals superior performance of the new Ir(iii) complex.

AB - In this paper, we present the synthesis and characterization of a new highly phosphorescent cyclometalated Ir(iii) complex with a silane-based dendritic substituent. The Ir(iii) complex showed 74 ± 3% of absolute phosphorescence quantum efficiency in the film state. In addition, efficient electrophosphorescence (32.8 cd A-1) employing an Ir(iii) complex-poly(N-vinylcarbazole) system device is observed. Study of a series of electroluminescent, spectroscopic, and electrochemical data of the Ir(iii) complex and the reference Ir(ppy)3 reveals superior performance of the new Ir(iii) complex.

UR - https://www.scopus.com/pages/publications/33845274066

U2 - 10.1039/b611288a

DO - 10.1039/b611288a

M3 - Article

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SN - 0959-9428

VL - 16

SP - 4706

EP - 4713

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 48

ER -

Silicon-containing dendritic tris-cyclometalated Ir(iii) complex and its electrophosphorescence in a polymer host

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